Primordial Martian Atmosphere had Little Carbon Dioxide?

The CO2 level in Mars' primitive atmosphere 3.5 billion years ago was too low for sediments, such as those found by NASA's Curiosity exploration vehicle in areas like the Gale Crater on the planet's equator, to be deposited. This and other conclusions are drawn from a paper written with the participation of researchers from the Spanish National Research Council (CSIC) and published in the latest issue of the journal, Proceedings of the National Academy of Sciences (PNAS).

The area Curiosity has been analysing since 2012, as part of NASA's Mars Science Laboratory mission, is composed primarily of sedimentary sequences deposited at the bottom of a lake 3.5 billion years ago. These sediments contain various secondary minerals, such as clays or sulphates, which indicate that the primitive surface was in contact with liquid water.

The existence of liquid water requires a warm surface temperature brought about by a minimum content of CO2 in the atmosphere. Yet this was not the case with Mars in its beginnings. "This contradiction has two possible solutions. Either we have not yet developed climatic models which explain the environmental conditions on Mars at the beginning of its history, or the Gale sedimentary sequences really did form in a very cold climate. The second option is the most reasonable", explains CSIC researcher Alberto Fairén, who works at the Centre for Astrobiology near Madrid (a joint centre run by CSIC and Spain's National Institute of Aerospace Technology).

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"However, the rover has not found carbonates, thereby confirming the results of studies by all previous probes: carbonates are very scarce on the surface of Mars and, therefore, the CO2 level in the atmosphere was very low", adds. Fairén.

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A Faint Young Sun Paradox Solution for Mars

Transient reducing greenhouse warming on early Mars

Authors:

Wordsworth et al

Abstract:

The evidence for abundant liquid water on early Mars despite the faint young Sun is a long-standing problem in planetary research. Here we present new ab initio spectroscopic and line-by-line climate calculations of the warming potential of reduced atmospheres on early Mars. We show that the strength of both CO2-H2 and CO2-CH4 collision-induced absorption (CIA) has previously been significantly underestimated. Contrary to previous expectations, methane could have acted as a powerful greenhouse gas on early Mars due to CO2-CH4 CIA in the critical 250-500 cm^-1 spectral window region. In atmospheres of 0.5 bar CO2 or more, percent levels of H2 or CH4 raise annual mean surface temperatures by tens of degrees, with temperatures reaching 273 K for pressures of 1.25-2 bar and 2-10% of H2 and CH4. Methane and hydrogen produced following aqueous alteration of Mars' crust could have combined with volcanically outgassed CO2 to form transient atmospheres of this composition 4.5-3.5 Ga. This scenario for the late Noachian climate can be tested via future in situ and orbital studies of the martian crust.

Was Early Martian Climate Cold but Warmed Periodically by Volcanism & Impacts?

Climate Cycling on Early Mars Caused by the Carbonate-Silicate Cycle

Authors:

Batalha et al

Abstract:

For decades, scientists have tried to explain the evidence for fluvial activity on early Mars, but a consensus has yet to emerge regarding the mechanism for producing it. One hypothesis suggests early Mars was warmed by a thick greenhouse atmosphere. Another suggests that early Mars was generally cold but was warmed occasionally by impacts or by episodes of enhanced volcanism. These latter hypotheses struggle to produce the amounts of rainfall needed to form the martian valleys, but are consistent with inferred low rates of weathering compared to Earth. Here, we provide a geophysical mechanism that could have induced cycles of glaciation and deglaciation on early Mars. Our model produces dramatic climate cycles with extended periods of glaciation punctuated by warm periods lasting up to 10 Myr, much longer than those generated in other episodic warming models. The cycles occur because stellar insolation was low, and because CO2 outgassing is not able to keep pace with CO2 consumption by silicate weathering followed by deposition of carbonates. While CO2 by itself is not able to deglaciate early Mars in our model, we assume that the greenhouse effect is enhanced by substantial amounts of H2 outgassed from Mars' reduced crust and mantle. Our hypothesis can be tested by future Mars exploration that better establishes the time scale for valley formation.

Could Cirrus Clouds Have Warmed Early Mars?

Could Cirrus Clouds Have Warmed Early Mars?

Authors:

Rameriz et al

Abstract:

The presence of the ancient valley networks on Mars indicates that the climate at 3.8 Ga was warm enough to allow substantial liquid water to flow on the martian surface for extended periods of time. However, the mechanism for producing this warming continues to be debated. One hypothesis is that Mars could have been kept warm by global cirrus cloud decks in a CO2-H2O atmosphere containing at least 0.25 bar of CO2 (Urata and Toon, 2013). Initial warming from some other process, e.g., impacts, would be required to make this model work. Those results were generated using the CAM 3-D global climate model. Here, we use a single-column radiative-convective climate model to further investigate the cirrus cloud warming hypothesis. Our calculations indicate that cirrus cloud decks could have produced global mean surface temperatures above freezing, but only if cirrus cloud cover approaches ~75 - 100% and if other cloud properties (e.g., height, optical depth, particle size) are chosen favorably. However, at more realistic cirrus cloud fractions, or if cloud parameters are not optimal, cirrus clouds do not provide the necessary warming, suggesting that other greenhouse mechanisms are needed.

The effect of dust on the martian polar vortices

The effect of dust on the martian polar vortices

Authors:

Guzewich et al

Abstract:

The influence of atmospheric dust on the dynamics and stability of the martian polar vortices is examined, through analysis of Mars Climate Sounder observations and MarsWRF general circulation model simulations. We show that regional and global dust storms produce “transient vortex warming” events that partially or fully disrupt the northern winter polar vortex for brief periods. Increased atmospheric dust heating alters the Hadley circulation and shifts the downwelling branch of the circulation poleward, leading to a disruption of the polar vortex for a period of days to weeks. Through our simulations, we find this effect is dependent on the atmospheric heating rate, which can be changed by increasing the amount of dust in the atmosphere or by altering the dust optical properties (e.g., single scattering albedo). Despite this, our simulations show that some level of atmospheric dust is necessary to produce a distinct northern hemisphere winter polar vortex.

Do Sand Dune Shapes Suggest Mars had a Thin Atmosphere by the end of the Noachian 3.7 Billion Years ago?

Large wind ripples on Mars: A record of atmospheric evolution

Authors:

Lapotre et al

Abstract:

Wind blowing over sand on Earth produces decimeter-wavelength ripples and hundred-meter– to kilometer-wavelength dunes: bedforms of two distinct size modes. Observations from the Mars Science Laboratory Curiosity rover and the Mars Reconnaissance Orbiter reveal that Mars hosts a third stable wind-driven bedform, with meter-scale wavelengths. These bedforms are spatially uniform in size and typically have asymmetric profiles with angle-of-repose lee slopes and sinuous crest lines, making them unlike terrestrial wind ripples. Rather, these structures resemble fluid-drag ripples, which on Earth include water-worked current ripples, but on Mars instead form by wind because of the higher kinematic viscosity of the low-density atmosphere. A reevaluation of the wind-deposited strata in the Burns formation (about 3.7 billion years old or younger) identifies potential wind-drag ripple stratification formed under a thin atmosphere.

Martian zeolites as a source of atmospheric methane

Martian zeolites as a source of atmospheric methane

Authors:

Mousis et al

Abstract:

The origin of the martian methane is still poorly understood. A plausible explanation is that methane could have been produced either by hydrothermal alteration of basaltic crust or by serpentinization of ultramafic rocks producing hydrogen and reducing crustal carbon into methane. Once formed, methane storage on Mars is commonly associated with the presence of hidden clathrate reservoirs. Here, we alternatively suggest that chabazite and clinoptilolite, which belong to the family of zeolites, may form a plausible storage reservoir of methane in the martian subsurface. Because of the existence of many volcanic terrains, zeolites are expected to be widespread on Mars and their Global Equivalent Layer may range up to more than ∼1 km, according to the most optimistic estimates. If the martian methane present in chabazite and clinoptilolite is directly sourced from an abiotic source in the subsurface, the destabilization of a localized layer of a few millimeters per year may be sufficient to explain the current observations. The sporadic release of methane from these zeolites requires that they also remained isolated from the atmosphere during its evolution. The methane release over the ages could be due to several mechanisms such as impacts, seismic activity or erosion. If the methane outgassing from excavated chabazite and/or clinoptilolite prevails on Mars, then the presence of these zeolites around Gale Crater could explain the variation of methane level observed by Mars Science Laboratory.

Martian Atmospheric Methane Might Come From Zeolites

Martian zeolites as a source of atmospheric methane

Authors:

Mousis et al

Abstract:

The origin of the martian methane is still poorly understood. A plausible explanation is that methane could have been produced either by hydrothermal alteration of basaltic crust or by serpentinization of ultramafic rocks producing hydrogen and reducing crustal carbon into methane. Once formed, methane storage on Mars is commonly associated with the presence of hidden clathrate reservoirs. Here, we alternatively suggest that chabazite and clinoptilolite, which belong to the family of zeolites, may form a plausible storage reservoir of methane in the martian subsurface. Because of the existence of many volcanic terrains, zeolites are expected to be widespread on Mars and their Global Equivalent Layer may range up to more than ∼1 km, according to the most optimistic estimates. If the martian methane present in chabazite and clinoptilolite is directly sourced from an abiotic source in the subsurface, the destabilization of a localized layer of a few millimeters per year may be sufficient to explain the current observations. The sporadic release of methane from these zeolites requires that they also remained isolated from the atmosphere during its evolution. The methane release over the ages could be due to several mechanisms such as impacts, seismic activity or erosion. If the methane outgassing from excavated chabazite and/or clinoptilolite prevails on Mars, then the presence of these zeolites around Gale Crater could explain the variation of methane level observed by Mars Science Laboratory.

Spin Orbit Coupling for ...Mars?

Orbit-spin coupling and the circulation of the Martian atmosphere

Authors:

Shirley et al

Abstract:

The physical origins of the observed interannual variability of weather and climate on Mars are poorly understood. In this paper we introduce a deterministic physical mechanism that may account for much of the variability of the circulation of the Mars atmosphere on seasonal and longer timescales. We derive a coupling expression linking orbital and rotational motions that produces an acceleration field varying with position and with time on and within a subject body. The spatially and temporally varying accelerations may interfere constructively or destructively with large-scale flows of geophysical fluids that are established and maintained by other means. The hypothesis predicts cycles of intensification and relaxation of circulatory flows of atmospheres on seasonal and longer timescales that are largely independent of solar forcing. The predictions of the hypothesis may be tested through numerical modeling. Examples from investigations of the atmospheric circulation of Mars are provided to illustrate qualitative features and quantitative aspects of the mechanism proposed. We briefly discuss the implications and applicability of the orbit-spin coupling hypothesis for planets other than Mars.

Could a Supernova Have Wiped Out the Martian Atmosphere?

Did high energy astrophysical sources contribute to Martian atmospheric loss?

Authors:

Atri et al

Abstract:

Mars is believed to have had a substantial atmosphere in the past. Atmospheric loss led to depressurization and cooling, and is thought to be the primary driving force responsible for the loss of liquid water from its surface. Recently, MAVEN observations have provided new insight into the physics of atmospheric loss induced by ICMEs and solar wind interacting with the Martian atmosphere. In addition to solar radiation, it is likely that its atmosphere has been exposed to radiation bursts from high-energy astrophysical sources which become highly probable on timescales of ~Gy and beyond. These sources are capable of significantly enhancing the rates of photoionization and charged particle-induced ionization in the upper atmosphere. Here, we explore the possibility of damage from Galactic Gamma Ray Bursts, nearby supernovae, encounter with dense interstellar clouds and extreme solar events. We use Monte Carlo simulations to model the interaction of charged particles and photons from astrophysical sources in the upper Martian atmosphere and discuss its implications on atmospheric loss.

Hypotheses for near-surface exchange of methane on Mars

Hypotheses for near-surface exchange of methane on Mars

Authors:

Hu et al

Abstract:

The Curiosity rover recently detected a background of 0.7 ppb and spikes of 7 ppb of methane on Mars. This in situ measurement reorients our understanding of the Martian environment and its potential for life, as the current theories do not entail any geological source or sink of methane that varies sub-annually. In particular, the 10-fold elevation during the southern winter indicates episodic sources of methane that are yet to be discovered. Here we suggest a near-surface reservoir could explain this variability. Using the temperature and humidity measurements from the rover, we find that perchlorate salts in the regolith deliquesce to form liquid solutions, and deliquescence progresses to deeper subsurface in the season of the methane spikes. We therefore formulate the following three testable hypotheses. The first scenario is that the regolith in Gale Crater adsorbs methane when dry and releases this methane to the atmosphere upon deliquescence. The adsorption energy needs to be 36 kJ/mol to explain the magnitude of the methane spikes, higher than existing laboratory measurements. The second scenario is that microorganisms convert organic matter in the soil to methane when they are in liquid solutions. This scenario does not require regolith adsorption, but entails extant life on Mars. The third scenario is that deep subsurface aquifers produce the bursts of methane. Continued in situ measurements of methane and water, as well as laboratory studies of adsorption and deliquescence, will test these hypotheses and inform the existence of the near-surface reservoir and its exchange with the atmosphere.

A Mechanism Behind the Martiian Dust Devils

Amplification of dust loading in Martian dust devils by self-shadowing

Authors:

Kuepper et al

Abstract:

Insolation of the Martian soil leads to a sub-surface overpressure due to thermal creep gas flow. This could support particle entrainment into the atmosphere. Short time shadowing e.g. by the traverse of a larger dust devil would enhance this effect. We find in microgravity experiments that mass ejection rates are increased by a factor of 10 for several seconds if a light source of 12.6 kW/m2 is turned off. Scaled to Mars this implies that self-shadowing of a partially opaque dust devil might lead to a strongly amplified flux of lifted material. We therefore suggest that self-shadowing might be a mechanism on Mars to increase the total dust loading of a dust devil and keep it self-sustained.

Mile High Mounds Created on Mars by Winds

New research has found that wind carved massive mounds of more than a mile high on Mars over billions of years. Their location helps pin down when water on the Red Planet dried up during a global climate change event.

The research was published in the journal Geophysical Research Letters, a journal of the American Geophysical Union, on March 31.

The findings show the importance of wind in shaping the Martian landscape, a force that, on Earth, is overpowered by other processes, said lead author Mackenzie Day, a graduate student at The University of Texas at Austin Jackson School of Geosciences.

"On Mars there are no plate-tectonics, and there's no liquid water, so you don't have anything to overprint that signature and over billions of years you get these mounds, which speaks to how much geomorphic change you can really instigate with just wind," Day said. "Wind could never do this on Earth because water acts so much faster, and tectonics act so much faster."

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Cometary sputtering of the Martian atmosphere during the Siding Spring encounter

Cometary sputtering of the Martian atmosphere during the Siding Spring encounter

Authors:

Wang et al

Abstract:

With the approach of the close encounter of comet Siding Spring with Mars, possible influences on the Martian atmosphere from the cometary coma are being explored. Here we describe the non-thermal atmospheric loss due to atmospheric sputtering produced by the impact of the coma material. We use an atmospheric sputtering model to simulate the effect of the incident neutral O and the pickup O+,+, produced by photodissociation of water and its products. With the relatively large encounter speed of 56 km/s at a close flyby altitude of ∼130,000 km, the sputtering escape rates from the coma can reach 2–3 times the incident gas fluxes. Thus, the passing of the cometary coma will lead to removal of Martian atmosphere instead of mass loading. If the cometary outgassing rate reaches 10View the MathML source28s−1, the sputtering from the extended coma could remove about 10 tons of Martian gases and deposit about 1 ton of external cometary material into the atmosphere during the one hour encounter. This implies that the cometary sputtering may have played a non-negligible role in Mars atmospheric evolution when this kind of cometary encounter may occur frequently in early Martian epochs.

Simulating the Atmosphere of the Martian Northern Hemisphere

The variability, structure and energy conversion of the northern hemisphere traveling waves simulated in a Mars general circulation model

Authors:

Wang et al

Abstract:

Investigations of the variability, structure and energetics of the m = 1−3 traveling waves in the northern hemisphere of Mars are conducted with the MarsWRF general circulation model. Using a simple, annually repeatable dust scenario, the model reproduces many general characteristics of the observed traveling waves. The simulated m = 1 and m = 3 traveling waves show large differences in terms of their structures and energetics. For each representative wave mode, the geopotential signature maximizes at a higher altitude than the temperature signature, and the wave energetics suggests a mixed baroclinic-barotropic nature. There is a large contrast in wave energetics between the near-surface and higher altitudes, as well as between the lower latitudes and higher latitudes at high altitudes. Both barotropic and baroclinic conversions can act as either sources or sinks of eddy kinetic energy. Band-pass filtered transient eddies exhibit strong zonal variations in eddy kinetic energy and various energy transfer terms. Transient eddies are mainly interacting with the time mean flow. However, there appear to be non-negligible wave-wave interactions associated with wave mode transitions. These interactions include those between traveling waves and thermal tides and those among traveling waves.

The Predicted Interaction of Lava and Glaciers on Early Mars

Lava heating and loading of ice sheets on early Mars: Predictions for meltwater generation, groundwater recharge, and resulting landforms

Authors:

Cassanelli et al

Abstract:

Recent modeling studies of the early Mars climate predict a predominantly cold climate, characterized by the formation of regional ice sheets across the highland areas of Mars. Formation of the predicted “icy highlands” ice sheets is coincident with a peak in the volcanic flux of Mars involving the emplacement of the Late Noachian – Early Hesperian ridged plains unit. We explore the relationship between the predicted early Mars “icy highlands” ice sheets, and the extensive early flood volcanism to gain insight into the surface conditions prevalent during the Late Noachian to Early Hesperian transition period. Using Hesperia Planum as a type area, we develop an ice sheet lava heating and loading model. We quantitatively assess the thermal and melting processes involved in the lava heating and loading process following the chronological sequence of lava emplacement. We test a broad range of parameters to thoroughly constrain the lava heating and loading process and outline predictions for the formation of resulting geological features. We apply the theoretical model to a study area within the Hesperia Planum region and assess the observed geology against predictions derived from the ice sheet lava heating and loading model. Due to the highly cratered nature of the Noachian highlands terrain onto which the volcanic plains were emplaced, we predict highly asymmetrical lava loading conditions. Crater interiors are predicted to accumulate greater thicknesses of lava over more rapid timescales, while in the intercrater plains, lava accumulation occurs over longer timescales and does not reach great thicknesses. We find that top-down melting due to conductive heat transfer from supraglacial lava flows is generally limited when the emplaced lava flows are less than ∼10 m thick, but is very significant at lava flow thicknesses of ∼100 m or greater. We find that bottom-up cryosphere and ice sheet melting is most likely to occur within crater interiors where lavas accumulate to a sufficient thickness to raise the ice-melting isotherm to the base of the superposed lavas. In these locations, if lava accumulation occurs rapidly, bottom-up melting of the ice sheet can continue, or begin, after lava accumulation has completed in a process we term “deferred melting”. Subsurface mass loss through melting of the buried ice sheets is predicted to cause substantial subsidence in the superposed lavas, leading to the formation of associated collapse features including fracture systems, depressions, surface faulting and folding, wrinkle-ridge formation, and chaos terrain. In addition, if meltwater generated from the lava heating and loading process becomes trapped at the lava flow margins due to the presence of impermeable confining units, large highly pressurized episodic flooding events could occur. Examination of the study area reveals geological features which are generally consistent with those predicted to form as a result of the ice sheet lava heating and loading process, suggesting the presence of surface snow and ice during the Late Noachian to Early Hesperian period.

Argon isotopes as tracers for martian atmospheric loss

Argon isotopes as tracers for martian atmospheric loss

Authors:

Slipski et al

Abstract:

Recent measurements of the present-day Ar abundance and isotopic ratios in the martian atmosphere by the SAM instrument suite onboard the Curiosity rover can be used to constrain the atmospheric and volatile evolution. We have examined the role of volcanic outgassing, escape to space via sputtering, crustal erosion, impact delivery, and impact erosion in reproducing the Ar isotope ratios from an initial state 4.4 billion years ago. To investigate the effects of each of these processes, their timing, and their intensity we have modeled exchanges of Ar isotopes between various reservoirs (mantle, crust, atmosphere, etc.) throughout Mars’ history. Furthermore, we use present-day atmospheric measurements to determine the parameter space consistent with observations. We find that significant loss to space (at least 48% of atmospheric 36Ar) is required to match the observed 36Ar/38Ar ratio. Our estimates of volcanic outgassing do not supply sufficient 40Ar to the atmosphere to match observations, so in our model at least 31% of 40Ar produced in the crust must have also been released to the atmosphere. Of the total 40Ar introduced into the atmosphere about 25% must have been lost to space. By adding the present-day isotopic abundances with our results of total integrated Ar loss we find a “restored” value of atmospheric 40Ar/36Ar, which represents what that ratio would be if the total integrated Ar loss had remained in the atmosphere. We determine the restored value to be ∼900–1500. This is below the present martian atmospheric value (1900 ± 300), but 3–5 times greater than the terrestrial value.

Martian Atmosphere was Reducing (ie not oxidizing) Through the end of the Noachian Era, 3.7 Billion Years ago

Mineralogical record of the redox conditions on early Mars

Authors:

Dehouck et al

Abstract:

Sulfates and Fe-oxides identified on the martian surface by orbital and in situ missions indicate that oxidizing conditions have existed on early Mars, at least locally and/or episodically. In the context of rock alteration and weathering, redox conditions are especially critical for the behavior of iron, which is soluble in its divalent state but insoluble in its trivalent state. Here, we combine results from a series of laboratory experiments conducted under Mars-like conditions to address the influence of highly-oxidizing compounds such as hydrogen peroxide (H2O2) on the alteration pathways of primary materials. We show that, if early Mars had a dense CO2 atmosphere allowing for relatively “warm and wet” conditions and surface weathering, highly-oxidizing conditions would have strongly inhibited the formation of Fe/Mg-smectite clays from alteration of igneous ferromagnesian minerals, and possibly enhanced the formation of carbonates. But a decade of mineral mapping of the martian surface show abundant, widespread Fe/Mg-clays and rare carbonates, which we interpret here as a mineralogical record of poorly-oxidizing (or even reducing) conditions during most of the Noachian era. Oxidizing conditions would have occurred later in martian history as a consequence of a higher rate of H2 escape or of a lower rate of volcanic outgassing, or both.

Impacts by Comets and Asteroids Since the Noachian Probably NOT the Cause of Martian Atmospheric Loss

Scenarios of atmospheric mass evolution on Mars influenced by asteroid and comet impacts since the late Noachian

Authors:

Pham et al

Abstract:

Early in its history, Mars probably had a denser atmosphere and higher surface temperatures to sustain the presence of stable liquid water or saline solution at the surface. Impacts by asteroids and comets could affect the atmospheric evolution of a planet, by removing part of its atmosphere and by delivering into it material and volatiles. In this study we investigate the atmospheric loss and delivery of volatiles between the end of the Noachian and present, with the help of a semi-analytic model. Our results suggest that impacts alone can hardly remove a significant amount of atmospheric mass over this period. Contribution of additional factors such as outgassing and non-thermal escape processes can not explain neither the presence of surface pressure larger than few hundreds of mbars 3.9 Gyr ago, unless parameter values outside of their expected range are considered. Based on extreme case scenarios, maximum surface pressures at the end of the Noachian, could be as much as 0.25 bar or 1.9 bar, with and without CO2 storage into carbonate reservoirs, respectively.

Black Fungi From Antarctica Survived in Simulated Martian Conditions for 18 Months on the ISS

Survival of Antarctic Cryptoendolithic Fungi in Simulated Martian Conditions On Board the International Space Station

Authors:

Silvano et al

Abstract:

Dehydrated Antarctic cryptoendolithic communities and colonies of the rock inhabitant black fungi Cryomyces antarcticus (CCFEE 515) and Cryomyces minteri (CCFEE 5187) were exposed as part of the Lichens and Fungi Experiment (LIFE) for 18 months in the European Space Agency's EXPOSE-E facility to simulated martian conditions aboard the International Space Station (ISS). Upon sample retrieval, survival was proved by testing colony-forming ability, and viability of cells (as integrity of cell membrane) was determined by the propidium monoazide (PMA) assay coupled with quantitative PCR tests. Although less than 10% of the samples exposed to simulated martian conditions were able to proliferate and form colonies, the PMA assay indicated that more than 60% of the cells and rock communities had remained intact after the “Mars exposure.” Furthermore, a high stability of the DNA in the cells was demonstrated. The results contribute to assessing the stability of resistant microorganisms and biosignatures on the surface of Mars, data that are valuable information for further search-for-life experiments on Mars.