Methane Humidity Near TItan's Surface

The near-surface methane humidity on Titan

Authors:

Lora et al

Abstract:

We retrieve vertical and meridional variations of methane mole fraction in Titan's lower troposphere by re-analyzing near-infrared ground-based observations from 17 July 2014 UT (Adamkovics et al., 2016). We generate synthetic spectra using atmospheric methane profiles that do not contain supersaturation or discontinuities to fit the observations, and thereby retrieve minimum saturation altitudes and corresponding specific humidities in the boundary layer. We relate these in turn to surface-level relative humidities using independent surface temperature measurements. We also compare our results with general circulation model simulations to interpret and constrain the relationship between humidities and surface liquids. The results show that Titan's lower troposphere is undersaturated at latitudes south of 60N, consistent with a dry surface there, but increases in humidity toward the north pole indicate appreciable surface liquid coverage. While our observations are consistent with considerably more liquid methane existing at the north pole than is present in observed lakes, a degeneracy between low-level methane and haze leads to substantial uncertainty in determining the extent of the source region.

Was Titan's Nitrogen Atmosphere was Originally Ammonia?

Isotopic ratio of nitrogen on Titan: Photochemical interpretation

Author:

Krasnopolsky

Abstract:

Nitrogen isotope fractionation in predissociation of N2 (Liang et al., 2007) is combined with production of N(4S), N(2D), and N+ in dissociation and dissociative ionization by the solar EUV photons, photoelectrons, magnetospheric electrons and protons, and cosmic rays from the photochemical model. The calculated 14N/15N ratio in nitriles is 57, in excellent agreement with the observed ratio in HCN. Loss of nitrogen in condensation and polymerization of nitriles is 392 g cm−2 Byr−1 with nitrogen isotope fractionation factor of 2.8. Loss of nitrogen by sputtering is 57 g cm−2 Byr−1 (De La Haye et al., 2007) with fractionation factor of 0.73 (Mandt et al., 2014). If the current loss was constant throughout the age of the Solar System, then the initial 14N/15N ratio on Titan is 129, similar to 127±32 for ammonia in comets (Rousselot et al., 2014). However, the solar EUV and wind were stronger from the young Sun, and this tends to further reduce the initial 14N/15N ratio. Nevertheless uncertainties of the problem and of the ratio in comets support the idea that nitrogen on Titan appeared as ammonia ice with 14N/15N similar to that in comets.

A new astrobiological model of the atmosphere of Titan

A new astrobiological model of the atmosphere of Titan

Authors:

Willacy et al

Abstract:

We present results of an investigation into the formation of nitrogen-bearing molecules in the atmosphere of Titan. We extend a previous model (Li et al. 2015, 2016) to cover the region below the tropopause, so the new model treats the atmosphere from Titan's surface to an altitude of 1500 km. We consider the effects of condensation and sublimation using a continuous, numerically stable method. This is coupled with parameterized treatments of the sedimentation of the aerosols and their condensates, and the formation of haze particles. These processes affect the abundances of heavier species such as the nitrogen-bearing molecules, but have less effect on the abundances of lighter molecules. Removal of molecules to form aerosols also plays a role in determining the mixing ratios, in particular of HNC, HC3N and HCN. We find good agreement with the recently detected mixing ratios of C2H5CN, with condensation playing an important role in determining the abundance of this molecule below 500 km. Of particular interest is the chemistry of acrylonitrile (C2H3CN) which has been suggested by Stevenson et al. (2015) as a molecule that could form biological membranes in an oxygen-deficient environment. With the inclusion of haze formation we find good agreement of our model predictions of acrylonitrile with the available observations.

The Titan Winged Aerobot is an Intriguing Glider/Balloon Hybrid

With a suspected subterranean sea of liquid water, oceans of methane on the surface and an atmosphere that could give rise to non-water-based life, it's no surprise that scientists are keen to learn more about Saturn's moon Titan. To that end, a new joint project between the Global Aerospace Corporation (GAC) and Northrop Grumman Aerospace Systems (NGAS) is developing a new exploration vehicle designed to soar through the skies of that mysterious moon.

The proposed Titan Winged Aerobot (TWA) is inspired by Northrop Grumman's T-LEAF (Lifting Entry Atmospheric Flight) class of vehicles, which would allow the craft to gently enter the atmosphere before transitioning into flight mode. Once there, the TWA would operate like a hybrid balloon and glider, utilizing a unique buoyancy system to allow it to ascend and descend without the use of propulsion systems or flight control surfaces. Minimal moving parts means it could squeeze more juice out of a single radioisotope power source.

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The Cryogenic Prebiotic Chemistry of Titan

Polymorphism and electronic structure of polyimine and its potential significance for prebiotic chemistry on Titan

Authors:

Rahm et al

Abstract:

The chemistry of hydrogen cyanide (HCN) is believed to be central to the origin of life question. Contradictions between Cassini–Huygens mission measurements of the atmosphere and the surface of Saturn’s moon Titan suggest that HCN-based polymers may have formed on the surface from products of atmospheric chemistry. This makes Titan a valuable “natural laboratory” for exploring potential nonterrestrial forms of prebiotic chemistry. We have used theoretical calculations to investigate the chain conformations of polyimine (pI), a polymer identified as one major component of polymerized HCN in laboratory experiments. Thanks to its flexible backbone, the polymer can exist in several different polymorphs, which are relatively close in energy. The electronic and structural variability among them is extraordinary. The band gap changes over a 3-eV range when moving from a planar sheet-like structure to increasingly coiled conformations. The primary photon absorption is predicted to occur in a window of relative transparency in Titan’s atmosphere, indicating that pI could be photochemically active and drive chemistry on the surface. The thermodynamics for adding and removing HCN from pI under Titan conditions suggests that such dynamics is plausible, provided that catalysis or photochemistry is available to sufficiently lower reaction barriers. We speculate that the directionality of pI’s intermolecular and intramolecular =N–H…N hydrogen bonds may drive the formation of partially ordered structures, some of which may synergize with photon absorption and act catalytically. Future detailed studies on proposed mechanisms and the solubility and density of the polymers will aid in the design of future missions to Titan.

Dust From the Kuiper Belt Produces Benzene in Titan's Atmosphere

Uptake of acetylene on cosmic dust and production of benzene in Titan's atmosphere

Authors:

Frankland et al

Abstract:

A low-temperature flow tube and ultra-high vacuum apparatus were used to explore the uptake and heterogeneous chemistry of acetylene (C2H2) on cosmic dust analogues over the temperature range encountered in Titan's atmosphere below 600 km. The uptake coefficient, γ, was measured at 181 K to be (1.6 ± 0.4) × 10-4, (1.9 ± 0.4) × 10−4 and (1.5 ± 0.4) × 10−4 for the uptake of C2H2 on Mg2SiO4, MgFeSiO4 and Fe2SiO4, respectively, indicating that γ is independent of Mg or Fe active sites. The uptake of C2H2 was also measured on SiO2 and SiC as analogues for meteoric smoke particles in Titan's atmosphere, but was found to be below the detection limit (γ < 6 × 10−8 and < 4 × 10-7, respectively). The rate of cyclo-trimerization of C2H2 to C6H6 was found to be 2.6 × 10-5 exp(-741/T) s−1, with an uncertainty ranging from ± 27 % at 115 K to ± 49 % at 181 K. A chemical ablation model was used to show that the bulk of cosmic dust particles (radius 0.02–10 µm) entering Titan's atmosphere do not ablate (< 1% mass loss through sputtering), thereby providing a significant surface for heterogeneous chemistry. A 1D model of dust sedimentation shows that the production of C6H6via uptake of C2H2 on cosmic dust, followed by cyclo-trimerization and desorption, is probably competitive with gas-phase production of C6H6 between 80 and 120 km.

Titan's organic aerosols

Titan's organic aerosols: Molecular composition and structure of laboratory analogues inferred from pyrolysis gas chromatography mass spectrometry analysis

Authors:

Morrisson et al

Abstract:

Analogues of Titan's aerosols are of primary interest in the understanding of Titan's atmospheric chemistry and climate, and in the development of in situ instrumentation for future space missions. Numerous studies have been carried out to characterize laboratory analogues of Titan aerosols (tholins), but their molecular composition and structure are still poorly known. If pyrolysis gas chromatography mass spectrometry (pyr-GCMS) has been used for years to give clues about their chemical composition, highly disparate results were obtained with this technique. They can be attributed to the variety of analytical conditions used for pyr-GCMS analyses, and/or to differences in the nature of the analogues analyzed, that were produced with different laboratory set-ups under various operating conditions.

In order to have a better description of Titan's tholin's molecular composition by pyr-GCMS, we carried out a systematic study with two major objectives: (i) exploring the pyr-GCMS analytical parameters to find the optimal ones for the detection of a wide range of chemical products allowing a characterization of the tholins composition as comprehensive as possible, and (ii) highlighting the role of the CH4 ratio in the gaseous reactive medium on the tholin's molecular structure. We used a radio-frequency plasma discharge to synthetize tholins with different concentrations of CH4 diluted in N2. The samples were pyrolyzed at temperatures covering the 200–700°C range. The extracted gases were then analyzed by GCMS for their molecular identification.

The optimal pyrolysis temperature for characterizing the molecular composition of our tholins by GCMS analysis is found to be 600°C. This temperature choice results from the best compromise between the number of compounds released, the quality of the signal and the appearance of pyrolysis artifacts. About a hundred molecules are identified as pyrolysates. A common major chromatographic pattern appears clearly for all the samples even if the number of released compounds can significantly differ. The hydrocarbon chain content increases in tholins when the CH4 ratio increases. A semi-quantitative study of the nitriles (most abundant chemical family in our chromatograms) released during the pyrolysis shows the existence of a correlation between the amount of a nitrile released and its molecular mass, similarly to the previous quantification of nitriles in the plasma gas-phase. Moreover, numerous nitriles are present both in tholins and in the gas phase, confirming their suspected role in the gas phase as precursors of the solid organic particles.

THE ROLE OF NITROGEN IN TITAN'S UPPER ATMOSPHERIC HYDROCARBON CHEMISTRY OVER THE SOLAR CYCLE

THE ROLE OF NITROGEN IN TITAN'S UPPER ATMOSPHERIC HYDROCARBON CHEMISTRY OVER THE SOLAR CYCLE

Authors:

Luspay-Kuti et al

Abstract:

Titan's thermospheric photochemistry is primarily driven by solar radiation. Similarly to other planetary atmospheres, such as Mars', Titan's atmospheric structure is also directly affected by variations in the solar extreme-UV/UV output in response to the 11-year-long solar cycle. Here, we investigate the influence of nitrogen on the vertical production, loss, and abundance profiles of hydrocarbons as a function of the solar cycle. Our results show that changes in the atmospheric nitrogen atomic density (primarily in its ground state N(4S)) as a result of photon flux variations have important implications for the production of several minor hydrocarbons. The solar minimum enhancement of CH3, C2H6, and C3H8, despite the lower CH4 photodissociation rates compared with solar maximum conditions, is explained by the role of N(4S). N(4S) indirectly controls the altitude of termolecular versus bimolecular chemical regimes through its relationship with CH3. When in higher abundance during solar maximum at lower altitudes, N(4S) increases the importance of bimolecular CH3 + N(4S) reactions producing HCN and H2CN. The subsequent remarkable CH3 loss and decrease in the CH3 abundance at lower altitudes during solar maximum affects the overall hydrocarbon chemistry.

Characterizing Titan's Atmospheric Aerosols

Characterization of aromaticity in analogues of titan's atmospheric aerosols with two-step laser desorption ionization mass spectrometry

Authors:

Mahjoub et al

Abstract:

The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric emission band observed by the Visible and Infrared Mapping Spectrometer (VIMS) at 3.28 micrometer suggests the presence of neutral polycyclic aromatic species in the upper atmosphere of Titan. These molecules are seen as the counter part of negative and positive aromatics ions suspected by the Plasma Spectrometer onboard the Cassini spacecraft, but the low resolution of the instrument hinders any molecular speciation.

In this work we investigate the specific aromatic content of Titan's atmospheric aerosols through laboratory simulations. We report here the selective detection of aromatic compounds in tholins, Titan's aerosol analogues, produced with a capacitively coupled plasma in a N2:CH4 95:5 gas mixture. For this purpose, Two-Step Laser Desorption Ionization Time-of-Flight Mass Spectrometry (L2DI-TOF-MS) technique is used to analyze the so produced analogues. This analytical technique is based on the ionization of molecules by Resonance Enhanced Multi-Photon Ionization (REMPI) using a {\lambda}=248 nm wavelength laser which is selective for aromatic species. This allows for the selective identification of compounds having at least one aromatic ring. Our experiments show that tholins contain a trace amount of small PAHs with one to three aromatic rings. Nitrogen containing PAHs (PANHs) are also detected as constituents of tholins. Molecules relevant to astrobiology are detected as is the case of the substituted DNA base adenine.

Where is Titan's Missing Ethane?

Titan’s missing ethane: From the atmosphere to the subsurface

Authors:

Gilliam et al

Abstract:

The second most abundant component of the present-day Titan atmosphere, methane (CH4), is known to undergo photolytic conversion to ethane (C2H6) that accumulates as a liquid on Titan’s surface. Condensation temperature of ethane is higher than that of methane, so that ethane “rain” may be expected to occur before the liquefaction of methane. At present, the partial pressure of ethane in the atmosphere is 1E−5 bar, much lower than 1E−1 bar of CH4. Estimated 8.46E17 kg or 1.37E6 km3 of C2H6 have been produced on Titan since accretion. The Titan surface reservoirs of ethane are lakes and craters, of estimated volume of 50,000 km3 and 61,000 km3, respectively. As these are smaller than the total volume of liquid ethane produced in the course of Titan’s history, the excess may be stored in the subsurface of the crust, made primarily of water ice. The minimum porosity of the crust needed to accommodate all the liquid ethane would be only 0.9% of the uppermost 2 km of the crust. The occurrence of CH4 and liquid C2H6 on Titan has led to much speculation on the possibility of life on that satellite. The aggregation of organic molecules in a “primordial soup or bullion” depends in part on the viscosity of the medium, diffusivity of organic molecules in it, and rates of polymerization reactions. The temperatures on Titan, much lower than on primordial Earth, are less favorable to the “Second Coming of life” on Titan.

Search for methane isotope fractionation due to Rayleigh distillation on Titan

Search for methane isotope fractionation due to Rayleigh distillation on Titan

Authors:

Ádámkovics et al

Abstract:

We search for meridional variation in the abundance of CH3D relative to CH4 on Titan using near-IR spectra obtained with NIRSPAO at Keck, which have a photon-limited signal-to-noise ratio of ∼50. Our observations can rule out a larger than 10% variation in the column of CH3D below 50 km. The preferential condensation of the heavy isotopologues will fractionate methane by reducing CH3D in the remaining vapor, and therefore these observations place limits on the amount of condensation that occurs in the troposphere. While previous estimates of CH3D fractionation on Titan have estimated an upper limit of -6 per mil, assuming a solid condensate, we consider more recent laboratory data for the equilibrium fractionation over liquid methane, and use a Rayleigh distillation model to calculate fractionation in an ascending parcel of air that is following a moist adiabat. We find that deep, precipitating convection can enhance the fractionation of the remaining methane vapor by -10 to -40 per mil, depending on the final temperature of the rising parcel. By relating fractionation of our reference parcel model to the pressure level where the moist adiabat achieves the required temperature, we argue that the measured methane fractionation constrains the outflow level for a deep convective event. Observations with a factor of at least 4 to 6 times larger signal-to-noise are required to detect this amount of fractionation, depending on the altitude range over which the outflow from deep convection occurs.

Cryolava flow destabilization of crustal methane clathrate hydrate on Titan

Cryolava flow destabilization of crustal methane clathrate hydrate on Titan

Authors:

Davies et al

Abstract:

To date, there has been no conclusive observation of ongoing endogenous volcanic activity on Saturn's moon Titan. However, with time, Titan's atmospheric methane is lost and must be replenished. We have modeled one possible mechanism for the replenishment of Titan's methane loss. Cryolavas can supply enough heat to release large amounts of methane from methane clathrate hydrates (MCH). The volume of methane released is controlled by the flow thickness and its areal extent. The depth of the destabilisation layer is typically ≈30% of the thickness of the lava flow (≈3 m for a 10-m thick flow). For this flow example, a maximum of 372 kg of methane is released per m2 of flow area. Such an event would release methane for nearly a year. One or two events per year covering ∼20 km2 would be sufficient to resupply atmospheric methane. A much larger effusive event covering an area of ≈9000 km2 with flows 200 m thick would release enough methane to sustain current methane concentrations for 10,000 years. The minimum size of “cryo-flows” sufficient to maintain the current atmospheric methane is small enough that their detection with current instruments (e.g., Cassini) could be challenging. We do not suggest that Titan's original atmosphere was generated by this mechanism. It is unlikely that small-scale surface MCH destabilisation is solely responsible for long-term (greater than a few Myr) sustenance of Titan's atmospheric methane, but rather we present it as a possible contributor to Titan's past and current atmospheric methane.

Modeling Titan's Upper Atmosphere

Examining the exobase approximation: DSMC models of Titan's upper atmosphere

Authors:

Tucker et al

Abstract:

Chamberlain ([1963] Planet. Space Sci., 11, 901–960) described the use of the exobase layer to determine escape from planetary atmospheres, below which it is assumed that molecular collisions maintain thermal equilibrium and above which collisions are deemed negligible. De La Haye et al. ([2007] Icarus., 191, 236–250) used this approximation to extract the energy deposition and non-thermal escape rates for Titan's atmosphere by fitting the Cassini Ion Neutral Mass Spectrometer (INMS) density data. De La Haye et al. assumed the gas distributions were composed of an enhanced population of super-thermal molecules (E >> kT) that could be described by a kappa energy distribution function (EDF), and they fit the data using the Liouville theorem. Here we fitted the data again, but we used the conventional form of the kappa EDF. The extracted kappa EDFs were then used with the Direct Simulation Monte Carlo (DSMC) technique (Bird [1994] Molecular Gas Dynamics and the Direct Simulation of Gas Flows) to evaluate the effect of collisions on the exospheric profiles. The INMS density data can be fit reasonably well with thermal and various non-thermal EDFs. However, the extracted energy deposition and escape rates are shown to depend significantly on the assumed exobase altitude, and the usefulness of such fits without directly modeling the collisions is unclear. Our DSMC results indicate that the kappa EDFs used in the Chamberlain approximation can lead to errors in determining the atmospheric temperature profiles and escape rates. Gas kinetic simulations are needed to accurately model measured exospheric density profiles, and to determine the altitude ranges where the Liouville method might be applicable.

Ground Fog Detected on Titan?

Possible ground fog detection from SLI imagery of Titan

Authors:

Smith et al

Abstract:

Titan, with its thick, nitrogen-dominated atmosphere, has been seen from satellite and terrestrial observations to harbour methane clouds. To investigate whether atmospheric features such as clouds could also be visible from the surface of Titan, data taken with the Side Looking Imager (SLI) on-board the Huygens probe after landing have been analysed to identify any potential atmospheric features. In total, 82 SLI images were calibrated, processed and examined for features. The calibrated images show a smooth vertical radiance gradient across the images, with no other discernible features. After mean-frame subtraction, six images contained an extended, horizontal feature that had a radiance value that lay outside the 95% confidence limit of the predicted radiance when compared to regions higher and lower in the images. The change in optical depth of these features were found to be between 0.005 and 0.014. It is considered that these features most likely originate from the presence of a fog bank close to the horizon that rises and falls during the period of observation.

How Titan's Early Atmosphere Evolved

Evolution of an early Titan atmosphere

Authors:

Johnson et al

Abstract:

Rapid escape from a proposed early CH4/NH3 atmosphere on Titan could, in principle, limit the amount of NH3 that is converted by photolysis into the present N2 atmosphere. Assuming that this conversion occurred, a recent estimate of escape driven by the surface temperature and pressure was used to constrain Titan's accretion temperature. Here we show that for the range of temperatures of interest, heating of the surface is not the primary driver for escape. Atmospheric loss from a thick Titan atmosphere is predominantly driven by heating of the upper atmosphere; therefore, the loss rate cannot be used to easily constrain the accretion temperature. We give an estimate of the solar driven escape rate from an early atmosphere on Titan, and then briefly discuss its relevance to the cooling rate, isotope ratios, and the time period suggested to convert NH3 to the present N2 atmosphere.

The Eclipses at Equinox Will Effect Titan's Climate

Eclipse-induced changes of Titan's meteorology at equinox

Authors:

Tokano et al

Abstract:

Titan experiences solar eclipses by Saturn on ∼20 consecutive orbits around equinox for durations of up to ∼6 hours. The impact of these eclipses on Titan's surface, lower atmosphere and middle atmosphere is investigated by a global climate model. When an eclipse commences, the surface temperature on the subsaturnian side drops by up to 0.3 K, so that the diurnal maximum surface temperature remains lower than on the antisaturnian side, which is never eclipsed. By contrast, the tropospheric air temperature does not abruptly decrease during the eclipses because of the large thermal inertia, but the diurnal mean temperature slightly decreases. The surface wind at low latitudes becomes less gusty in the presence of eclipse due to damping of turbulence. The troposphere outside the planetary boundary layer is not sensitive to eclipses. In most parts of the stratosphere and mesosphere the temperature decreases by up to 2 K due to eclipses, but there are also layers, which experience relative warming due to thermal contraction of the underlying layers. The temperature in the middle atmosphere rapidly recovers after the end of the eclipse season. Eclipse-induced cooling and warming changes the zonal wind speed by a few m s−1 due to thermal wind adjustment to changing latitudinal temperature gradients.

Simulating Titan's Methane Cycle

Simulating Titan’s methane cycle with the TitanWRF General Circulation Model

Authors:

Newman et al

Abstract:

Observations provide increasing evidence of a methane hydrological cycle on Titan. Earth-based and Cassini-based monitoring has produced data on the seasonal variation in cloud activity and location, with clouds being observed at increasingly low latitudes as Titan moved out of southern summer. Lakes are observed at high latitudes, with far larger lakes and greater areal coverage in the northern hemisphere, where some shorelines extend down as far as 50°N. Rainfall at some point in the past is suggested by the pattern of flow features on the surface at the Huygens landing site, while recent rainfall is suggested by surface change. As with the water cycle on Earth, the methane cycle on Titan is both impacted by tropospheric dynamics and likely able to impact this circulation via feedbacks. Here we use the 3D TitanWRF General Circulation Model (GCM) to simulate Titan’s methane cycle. In this initial work we use a simple large-scale condensation scheme with latent heat feedbacks and a finite surface reservoir of methane, and focus on large-scale dynamical interactions between the atmospheric circulation and methane, and how these impact seasonal changes and the long term (steady state) behavior of the methane cycle. We note five major conclusions: (1) Condensation and precipitation in the model is sporadic in nature, with interannual variability in its timing and location, but tends to occur in association with both (a) frequent strong polar upwelling during spring and summer in each hemisphere, and (b) the Inter-Tropical Convergence Zone (ITCZ), a region of increased convergence and upwelling due to the seasonally shifting Hadley cells. (2) An active tropospheric methane cycle affects the stratospheric circulation, slightly weakening the stratospheric superrotation produced. (3) Latent heating feedback strongly influences surface and near-surface temperatures, narrowing the latitudinal range of the ITCZ, and changing the distribution – and generally weakening the strength – of upwelling events. (4) TitanWRF favors low latitude ‘cloudiness’ around northern spring equinox as the ITCZ moves from south to north across the equator, versus the opposite time of year. (5) TitanWRF produces drying of low and mid latitudes with net transport of surface methane to high latitudes, and shows persistent hemispheric asymmetry in the methane cycle such that the favored pole for surface methane is the one with winter occurring closest to perihelion.

Titan has Developed a Huge South Pole Ice Cloud

NASA’s Cassini spacecraft has detected a massive, never-before-seen icy cloud at the south pole of Saturn’s huge moon Titan.

The newly spotted feature—part of a cloud system known as the south polar vortex—suggests that winter in the southern hemisphere of Titan will be even colder than predicted, scientists said.

The atmospheric signal “looks pretty normal, then BOOM!, increases,” indicating the presence of a brand-new cloud, said Cassini participating scientist Carrie Anderson, of NASA’s Goddard Space Flight Center in Greenbelt, Maryland. “I was so excited, I pretty much fell out of my chair.”

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Atmospheric Organic Polymers may be Raining out on Titan, Contributing to Titan's Dunes

Electron-molecule chemistry and charging processes on organic ices and Titan’s icy aerosol surrogates

Authors:

Pirim et al

Abstract:

Electron-induced polymerization processes and charging events that can occur within Titan’s atmosphere or on its surface were simulated using electron irradiation and dissociative electron attachment (DEA) studies of nitrogen-containing organic condensates. The DEA studies probe the desorption of H− from hydrogen cyanide (HCN), acetonitrile (CH3CN), and aminoacetonitrile (NH2CH2CN) ices, as well as from synthesized tholin materials condensed or deposited onto a graphite substrate maintained at low temperature (90–130 K). The peak cross sections for H− desorption during low-energy (3–15 eV) electron irradiation were measured and range from 3 × 10−21 to 2 × 10−18 cm2. Chemical and structural transformations of HCN ice upon 2 keV electron irradiation were investigated using X-ray photoelectron and Fourier-transform infrared spectroscopy techniques. The electron-beam processed materials displayed optical properties very similar to tholins produced by conventional discharge methods. Electron and negative ion trapping lead to 1011 charges cm−2 on a flat surface which, assuming a radius of 0.05 μm for Titan aerosols, is ∼628 charges/radius (in μm). The facile charge trapping indicates that electron interactions with nitriles and complex tholin-like molecules could affect the conductivity of Titan’s atmosphere due to the formation of large negative ion complexes. These negatively charged complexes can also precipitate onto Titan’s surface and possibly contribute to surface reactions and the formation of dunes.

The Effects of Late Heavy Bombardment on Titan's Atmopshere

Evolution of Titan’s atmosphere during the Late Heavy Bombardment

Authors:

Marounina et al

Abstract:

The mass and composition of Titan’s massive atmosphere, which is dominated by N2 and CH4 at present, have probably varied all along its history owing to a combination of exogenous and endogenous processes. In the present study, we investigate its fate during the Late Heavy Bombardment (LHB) by modeling the competitive loss and supply of volatiles by cometary impacts and their consequences on the atmospheric balance. For surface albedos ranging between 0.1 and 0.7, we examine the emergence of an atmosphere during the LHB as well as the evolution of a primitive atmosphere with various masses and compositions prior to this event, accounting for impact-induced crustal NH3–N2 conversion and subsequent outgassing as well as impact-induced atmospheric erosion. By considering an impactor population characteristic of the LHB, we show that the generation of a N2-rich atmosphere with a mass equivalent to the present-day one requires ammonia mass fraction of 2–5%, depending on surface albedos, in an icy layer of at least 50 km below the surface, implying an undifferentiated interior at the time of LHB. Except for high surface albedos (AS⩾0.7AS⩾0.7) where most of the released N2 remain frozen at the surface, our calculations indicate that the high-velocity impacts led to a strong atmospheric erosion. For a differentiated Titan with a thin ammonia-enriched crust (⩽5 km) and AS less than 0.6AS less than 0.6, any atmosphere preexisting before the LHB should be more than 5 times more massive than at present, in order to sustain an atmosphere equivalent to the present-day one. This implies that either a massive atmosphere was formed on Titan during its accretion or that the nitrogen-rich atmosphere was generated after the LHB.