Showing posts with label Neoarchean. Show all posts
Showing posts with label Neoarchean. Show all posts

Friday, December 16, 2016

Single Celled Organism Fossils From the NeoArchean of South Africa

When you think about the basic ingredients for life to thrive on Earth, no doubt water and oxygen pop to mind. But there was a time on our planet when our atmosphere only had one-one thousandth of one percent of the amount of oxygen it has now, yet there were plenty of life forms around then too, although proof of them has been scarce. A recent discovery of fossilized bacteria dating to about 2.5 billion years ago provides long-sought-for evidence that the Earth was crawling with life even though it lacked much oxygen during a phase in our planet's development known as the Neoarchean Eon.

"These fossils represent the oldest known organisms that lived in a very dark, deep-water environment," says Andrew Czaja, the assistant professor of geology at the University of Cincinnati in the US who made the discovery. "These bacteria existed two billion years before plants and trees, which evolved about 450 million years ago. We discovered these microfossils preserved in a layer of hard silica-rich rock called chert located within the Kaapvaal craton of South Africa."

Friday, October 28, 2016

Evidence of Sulfur Oxidizing Bacteria Prior to the Great Oxidation Event


Authors:

Czaja et al

Abstract:

The first 2 b.y. of Earth's history was an important time for life when microbes evolved and diversified into essentially all of the metabolic forms that now exist. Because of feedbacks between biology and the surface environment, understanding Earth's biological history can help us understand the evolution of Earth itself. The morphological and geochemical evidence for this ancient biological history is sparse but is increasing. Here we report evidence for 2.52 Ga exceptionally large, organic, smooth-walled, coccoidal microfossils preserved in a deep-water black chert in the Gamohaan Formation of the Kaapvaal craton of South Africa. These fossils occur mainly as compressed solitary coccoids that range in size from 20 to 265 μm but occasionally occur in short chains of cells. Morphologically these fossils are similar to Proterozoic and Phanerozoic acritarchs and to certain Archean fossils interpreted as possible cyanobacteria. However, their exceptionally large size, simple cell wall microstructure, and paleoecological setting, as well as multiple sulfur isotope systematics of pyrite within the unit, suggest that the Gamohaan Formation fossils were sulfur-oxidizing bacteria similar to those of the modern genus Thiomargarita, organisms that live in anoxic and sulfidic deepwater settings. These are the oldest reported fossil sulfur bacteria and reveal a diversity of life and ecosystems, previously only interpreted from geochemical proxies, just prior to the Great Oxidation Event, a time of major atmospheric evolution.

Friday, October 07, 2016

Evidence of Eukaryote Fossils From the NeoArchean?


Authors:

Kaźmierczak et al

Abstract:

Unequivocal evidence for Archean eukaryotic life has been long sought for and is a matter of lively debate. In the absence of unambiguous fossils this debate has focused on biogeochemical signatures and molecular phylogenies. Most researchers agree that fossil forms comparable with modern eukaryotic cells can be credibly identified only in Proterozoic (∼1.8-1.6 Ga) and younger rocks. Herein, we report for the first time, Neoarchean mineralized tubular microfossils from ∼2.8-2.7 Ga lacustrine deposits of South Africa. The exceptional preservation of these microfossils allows recognition of important morphological details in petrographic thin section and in HF-macerates that links them to modern siphonous (coenocytic) green or yellow-green microalgae (Chlorophyta and Xanthophyta). The microfossil identification is supported by Raman spectroscopic analyses, EPMA, SEM/BSE and SEM/EDS microprobe analytical results, NanoSIMS elemental mapping and micro-tomographic sectioning of the thalli. All results point to indigenous, bona fide eukaryotic microfossils of algal affinity. These Neoarchean microalgae-like remains and their assumingly combined in vivo and early post-mortem precipitated mineral envelopes greatly improve our knowledge of early life and its habitats and may have far-reaching consequences for the studies of the evolution of life.

Thursday, August 11, 2016

Evidence of an Impact Produced Polymorph in NeoArchean Spherules

Shock-metamorphosed rutile grains containing the high-pressure polymorph TiO2-II in four Neoarchean spherule layers

Authors:

Smith et al

Abstract:

At least 17 spherule layers are presently known within stratigraphic units deposited between ca. 3.47 and 2.49 Ga. The spherule layers contain varying amounts of formerly molten, millimeter-sized and smaller spherules. The aggregate thickness of spherules in these layers commonly ranges from ∼1 cm to as much as a few decimeters. Several lines of evidence support the interpretation that the spherule layers represent distal impact ejecta layers. Previously, only one shock-metamorphosed grain (quartz) had been documented from the spherule layers. Therefore, a key diagnostic criterion for the impact origin of these layers has remained elusive for 30 years. We report the discovery, using micro-Raman spectroscopy, of shock-induced TiO2-II, a high-pressure polymorph of TiO2, in 34 grains from four Neoarchean spherule layers deposited between ca. 2.65 and 2.54 Ga. As all the TiO2-II-bearing grains contain rutile, we interpret them as shock-metamorphosed rutile grains. Shock-metamorphosed rutile grains, which may be more abundant in the upper parts of three of the layers, provide unambiguous physical evidence to further support an impact origin for these four layers. Our results demonstrate that TiO2-II can survive for >2.5 b.y. in supracrustal successions that have undergone low-grade metamorphism. Because TiO2-II transforms to rutile at a temperature ≥440 °C, TiO2-II in impact ejecta layers is a potential geothermometer. To our knowledge, this is the first report of a shock-induced, high-pressure polymorph formed by an Archean impact.

Friday, May 13, 2016

Evidence of NeoArchean/PaleoProterozoic Crustal Reworking

Detrital zircon U-Pb ages and Hf isotopes of the metasedimentary rocks from the Jiaodong Group, Jiaobei terrane: Provenance and implications for the crustal evolution in the North China Craton

Authors:

Shan et al

Abstract:

Clastic sedimentary rocks can be a very powerful tool to gain insights into the crustal evolution history of many terranes. Here we present detrital zircon U-Pb ages and Hf isotopic data for the metasedimentary rocks in the Jiaobei terrane in the North China Craton (NCC), with a view to constrain the provenance of the protolith and depositional age, and to discuss implications for crustal evolution. The metasedimentary rocks in this study are similar to the sedimentary sequence of the Jiaodong Group in age populations of detrital zircons, petrology and mineralogy, and metamorphism and deformation, indicating that the studied samples belong to the sedimentary sequence of the Jiaodong Group. Detrital zircon U-Pb ages and Hf isotopic data of the metasedimentary rocks from the Jiaodong Group show similarity to those of the zircons from the Meoarchean-late Neoarchean granitoid gneisses in the Jiaobei terrane, suggesting that the Meoarchean-late Neoarchean granitoid gneisses in the Jiaobei terrane possibly provided the major source for the metasedimentary rocks of the Jiaodong Group. In combination with the previous studies, the detrital zircon populations in the Jiaobei terrane can place a good constraint on the depositional age of the Jiaodong Group. The youngest U-Pb age population of the magmatic detrital zircons (peak at 2489 Ma) is considered to constrain the maximum depositional age of the Jiaodong Group to 2.49 Ga. A major phase of metamorphism (late Paleoproterozoic) has been identified in the metasedimentary rocks of the Jiaodong Group, which mirrors the high-pressure granulite-facies regional metamorphism in the Jiaobei terrane. The magmatic detrital zircon Hf isotopes suggest that the zircons crystallized in magmas formed from the mixing of juvenile crustal components, including magmas derived from the depleted mantle, with ancient crustal materials. Therefore, our data suggest juvenile crustal growth and contemporaneous crustal reworking during the Neoarchean-Paleoproterozoic transition in the Jiaobei terrane.

Wednesday, May 11, 2016

Evidence of the First Continental Kernels From Archean China

U-Pb age and Hf isotopes of detrital zircons from the Southeastern North China Craton: Meso- to Neoarchean episodic crustal growth in a shifting tectonic regime

Auhtors:

Liu et al

Abstract:

The North China Craton (NCC) represents one of only a few cratonic nuclei on the globe with a geological history extending back to the Eoarchean. However, extensive ca. 2.5 Ga crustal reworking has destroyed a considerable portion of the pre-existing crustal record, hindering the investigation of tectonothermal evolution prior to 2.5 Ga. The Huoqiu Complex (HQC), located at the southeastern margin of the NCC, preserves the vestiges of crustal components that survived the ca. 2.5 Ga tectonothermal events, which provide the opportunity to investigate the Meso- to Neoarchean episodic crustal evolution of the NCC. Here we present results from in-situ detrital zircon U-Pb dating and Hf isotope analyses on zircons from three paragneisses in three drill cores that cut through the basement of the HQC. In combination with published data, the concordant age spectra of the detrital zircons in the paragneisses yield 207Pb/206Pb ages of 2343-3997 Ma that cluster into two principal age populations with peaks at 3015 and 2755 Ma. One zircon grain dated at 3997 ± 8 Ma with 98% concordance provides new evidence for 4.0 Ga components in the NCC. The εHf(t) values of all zircons range from -5.2 to + 6.5, with most of the spots (n = 31 of 47) showing positive values, indicating at least two episodes of juvenile continental crustal growth at 3.01 Ga and 2.75 Ga. The older episode is recorded only in few ancient cratons, suggesting limited crustal accretion occurred globally at a time of subdued mantle-derived magmatism. In contrast, the younger episode is coincident with a global rise in magmatic activity in the early Neoarchean. The geochemical and geochronological data suggest that the 3.01 Ga juvenile crust was likely generated in an island-arc subduction system, whereas the 2.75 Ga crustal rocks were probably formed during magmatic underplating and subsequent partial melting of lower crustal mafic rocks. Consequently, a tectonic transition is suggested from a compressive to an extensional setting along the southeastern margin of the NCC between 3.01 and 2.75 Ga. This sequence of events heralds a shift, from a mixture of net crustal growth and crustal reworking during multiple short-lived magmatic pulses, to fragmentation and dispersal of the early continental nucleus within 260 Ma.

Saturday, February 13, 2016

Pondering the Precambrian #2

Precambrian in General:


The magnetic field of the Earth has been surprisingly consistent over the course of Deep Time despite the changes happening internally.

Eukaryotes appear to have acquired mitochondria late in the process of their evolution away from other forms of life.

Studying modern stromatolites gives insight to Precambian life.

What meandering rivers prior to terrestrial plant life were like.

NeoProterozoic:

Was an increase in UV light caused by rapidly flipping magnetic poles the root cause of the Cambrian Explosion?

NeoArchean:

Cerium anomalies in from NeoArchean Brazil suggest the ocean was mildly oxygenated before the Great Oxygenation Event.

MesoArchean:

Evidence subduction (and plate tectonics) were active during the MesoArchean .

PaleoArchean:

Evidence from Swaziland suggests the minerals found there do NOT support subduction (and plate tectonics) as being their source as was apparently thought previously.

Doubt is being cast on PaleoArchean carbon deposits, trace evidence of microbes, being really from the PaleoArchean.

EoArchean:

There is evidence 'proto' crust may have existed 3.8 billion years ago.

Friday, January 01, 2016

Archaean Volcanic Sediment From MesoArchean to NeoArchean in Finland

U-Pb geochronology of Archaean volcanic-sedimentary sequences in the Kuhmo greenstone belt, Karelia Province–multiphase volcanism from Meso- to Neoarchaean and an Archaean depositional basin?

Authors:

Lehtonen et al

Abstract:

The Kuhmo greenstone belt in eastern Finland is one of the most studied areas of the Karelia Province. A single-grain zircon U-Pb study of andesitic, trachyandesitic and dacitic volcanic rocks from the belt demonstrates multiple widely spaced ages of the rocks. The results show that the volcanic activity took place as two major episodes at ca. 2847–2836 Ma and ca. 2799–2792 Ma, both containing komatiitic members as well as volcanic-sedimentary units. Based on the geochronological results combined with previously published data, we propose a chronostratigraphic interpretation for the Kuhmo greenstone belt, dividing it into three units: the Nuolikangas and Siivikkovaara volcanic units, and the sedimentary Ronkaperä unit. The results support the previous interpretation that age period of 2.80–2.79 Ga was an important crustal forming episode in the Kuhmo area. The zircon populations in the uppermost sedimentary rocks contain greater than 3.0 Ga zircon grains that are older than the volcanic rocks found in the greenstone belt. The youngest detrital zircon populations, ca. 2.73 Ga and 2.70 Ga in a conglomerate and quartz sandstone, respectively, imply that they were deposited at least ca. 60–90 Ma after the last volcanic phase. Based on the detrital zircon record, it can be interpreted that during the deposition of the detritus of the sedimentary rocks belonging to the Ronkaperä unit, the Karelia subprovinces were likely juxtaposed together and acted as a source provenance for the detritus.

Wednesday, December 30, 2015

More Evidence for Active Plate Tectonics and Subduction From NeoArchean/PaleoProterozoic North China

Petrology and geochemistry of the Guyang hornblendite complex in the Yinshan block, North China Craton: Implications for the melting of subduction-modified mantle

Abstract:

Ma et al

Abstract:

The hornblendite complexes hosted in the Guyang granite-greenstone terrane form part of the Neoarchean basement in the Western Block of the North China Craton. In this study, we focus on the largest one from this block, previously named the Guyang komatiite, and present results from lithological, geochronological and geochemical studies. The dominant lithology in the Guyang hornblendite complex is greenschist facies hornblendite, and can be divided into clinopyroxene hornblendite (∼75%) and olivine-orthopyroxene hornblendite (∼25%). The oldest calculated Re depletion model ages(TRD) of these hornblendites is of 2454 Ma, and the zircon U-Pb age of the wallrock is 2480 Ma, with single-stage depleted mantle Nd model ages TDM1(Nd) varying from 2.61 to 2.88 Ga. These data suggest that the Guyang hornblendite complexes formed during Neoarchean-Paleoproterozoic time. The hornblendites show low SiO2, high MgO contents and are enriched in Cr, Ni, and LREE with negative Ce anomalies and depleted in Ti, Nb and Ta. Their 187Os/188Os ratios range from 0.11145 to 0.11279, with γOs(2.5Ga) varying from −3.9 to +1.4. Geochemically, the olivine-orthopyroxene hornblendite shows little variation with typical cumulate feature. In contrast, the clinopyroxene hornblendite shows a large range of chemical variation. In the CaO vs. MgO and CaO/Al2O3 vs. MgO diagrams, the clinopyroxene hornblendite shows Opx fractionation trend. Combined with lithological information, we infer that the hornblendite magma was emplaced as a crystal mush, with orthopyroxene as cumulus phase. The Os and Nd isotope composition, negative Nb, Ta, Ce anomalies, and the relationships in Th/Yb-Nb/Yb diagram suggest that the Guyang hornblendites formed from a source mantle that was modified by subduction-related melts/fluids derived from a seawater-altered basaltic slab. Compared with typical Archean komatiites, the rocks of present study show significant differences in lithological and geochemical characteristics, and thus it cannot be named as komatiite. To explain these characteristics, we propose a geodynamic model involving ridge subduction and slab window mechanism to account for the formation of the Guyang hornblendite complex.

Sunday, December 27, 2015

Does the North China Craton Show Evidence of NeoArchean Microblock Amalgamation?

Neoarchean convergent margin tectonics associated with microblock amalgamation in the North China Craton: Evidence from the Yishui Complex

Authors:

Li et al

Abstract:

Archean tectonic history of the North China Craton (NCC) involved complex processes of amalgamation of microcontinents along multiple subduction zones prior to the consolidation of the major crustal blocks and their assembly into unified cratonic architecture. Here we report a suite of granitoids, diabase, metabasalts, volcanic tuff, banded iron formations and quartzite from the Yishui Complex along the southern margin of the Jiaoliao microblock within the Eastern Block of the NCC. The geochemical features of the magmatic suite are consistent with calc-alkaline magmatism in a convergent margin setting. In tectonic discrimination diagrams, the mafic suite shows variable IAB, MORB and OIB affinities typical of rocks formed in an arc-related subduction environment. Zircon grains in most of the rocks from Yishui Complex display core-rim texture with the cores showing magmatic crystallization and the narrow structureless rims corresponding to metamorphic overgrowth. The 207Pb/206Pb ages of magmatic zircons show 2504±19 Ma for the volcanic tuff, 2581±21 Ma for the granitoid, 2501±19 Ma for the metavolcanics, 2537±38 Ma for the pyroxenite, and 2506±13 Ma for the diabase. Metamorphism is constrained from the 2451±18 Ma and 2466±23 Ma age groups in the metavolcanics and (meta-) pyroxenites. Zircons from BIF show multiple population with the oldest showing a spot age of 2503 Ma, followed by a number of distinct groups of Paleoproterozoic zircons corresponding to later thermal events. The oldest population of magmatic zircons from the quartzite shows 207Pb/206Pb mean age of 2495±24 Ma. The dominantly positive εHf(t) values of the magmatic zircons from the Yishui suite are broadly consistent with a depleted mantle source with only minor input of crustal components. Their Hf crustal residence ages (TDMC) range from 2586 to 3181 Ma and Hf depleted mantle model ages(TDM) are in the range of 2548-2927 Ma. The data indicate that magma production involved Meso- to Neoarchean juvenile sources within a continental arc setting, suggesting the Jiaoliao microblock as one of the ancient continental nuclei in the NCC. We trace the continuity of a Neoarchean subduction system along the western and southern margins of the Jiaoliao microblock with convergence of the Qianhuai and Xuhuai microblocks towards the Jiaoliao microblock with subduction-accretion-collision during the Archean- Proterozoic transition

Saturday, December 26, 2015

Evidence of an Arc or Back Arc System From NeoArchean North China


A Neoarchean arc–back-arc system in Eastern Hebei, North China Craton: constraints from zircon U–Pb–Hf isotopes and geochemistry of dioritic–tonalitic–trondhjemitic–granodioritic (DTTG) gneisses and felsic paragneisses

Authors:
Bai et al

Abstract:

Dioritic–tonalitic–trondhjemitic–granodioritic (DTTG) gneisses are widely exposed in the Zunhua–Qinglong microblock of Eastern Hebei, North China Craton (NCC). LA–ICP–MS zircon U–Pb isotopic dating for the DTTG gneisses in the Qinglong area reveals that their magmatic precursors were emplaced between 2517 ± 10 and 2505 ± 23 Ma. Zircons of these DTTG gneisses exhibit positive ɛHf(t) values of 0.0 to +6.5, with adakite-like geochemical features represented by relatively high MgO, Mg# and (La/Yb)N ratios. Petrogenetic studies reveal that dioritic magmas were derived from depleted mantle peridotites that were strongly modified by slab-derived melts/fluids and that the tonalitic–trondhjemitic–granodioritic (TTG) magmas were formed by a high degree of fractional crystallization in the dioritic magmas with hornblende as the primary fractionated phase.

LA–ICP–MS zircon U–Pb isotopic analyses reveal that the protoliths of the felsic paragneisses in the Northern Zunhua area were deposited in the Late Neoarchean with a maximum depositional age of 2517 ± 20 Ma. Most of the detrital zircon grains display apparent 207Pb/206Pb ages from 3432 ± 20 to 2502 ± 21 Ma, with negative ɛHf(t) values of −15.4 to −2.4 and calculated TDMC ages between 3995 and 3368 Ma, suggesting that they were formed from the recycling of Eo- to Paleoarchean crustal materials closely related to the southeastern ancient continental crust of the interior Eastern Block. These data together with previous investigations reveal that the basement rocks of Zunhua–Qinglong microblock formed in a Neoarchean arc–back-arc system with the subduction direction from present northwest to southeast.

Tuesday, December 01, 2015

More Evidence of NeoArchean Subduction From the North China Craton


Discovery of Neoarchean suprasubduction zone ophiolite suite from Yishui Complex in the North China Craton

Authors:


Santosh et al

Abstract:

The Archean tectonic realm of the North China Craton (NCC) is considered in recent models as a collage of several microblocks which were amalgamated along zones of ocean closure during late Neoarchean. Here we report the finding of a dismembered ophiolite suite from the southern margin of the Jiaoliao microblock in the interior of the unified Eastern Block of the NCC. The suite is composed of lherzolite, pyroxenite, noritic and hornblende gabbro, and hornblendite intruded by veins and sheets of leuco granite. Together with transposed layers and bands of metavolcanics and amphibolites, banded iron formation (BIF), and diabase dykes in the adjacent locations, the Yishui complex corresponds well with a dismembered suprasubduction zone ophiolite suite. Clinopyroxene in the pyroxenite and gabbroic rocks are Mg rich and range in composition from augite to diopside. Among orthopyroxenes, those in lherzolite shows the highest XMg of 0.84-0.85. Plagioclase in hornblende gabbro shows high anorthite content (An50 -64). Calcic amphiboles in the gabbroic rocks range in composition from ferropargasite to ferro-edenite, edenite and pargasite. Spinel inclusions in lherzolite are Cr-rich magnesiospinel. Geochemically, the mafic rocks from Yishui complex show subalkaline basaltic source, whereas the granitoids show volcanic arc affinity. The hornblende gabbro and gabbro, lherzolite and hornblendite show compositional similarity to E-MORB and N-MORB respectively. The lherzolite and hornblendite possess arc-related ultramafic cumulate nature, with overall features straddling the fields of IAT and IAT-MORB. The geochemical features are consistent with evolution in a suprasubduction regime with no significant crustal contamination. The majority of zircon grains in the Yishui suite exhibit magmatic texture and high Th/U ratios. Zircon grains from hornblendite define 207Pb/206Pb upper intercept age of 2538 ± 30 Ma. Zircons from the granite show ages of 2538 ± 16 Ma and 2503 ± 21 Ma, and those from the gabbros yield ages of 2503 ± 16 Ma and 2495 ± 10 Ma. The well defined major age peak at 2500 Ma is broadly coeval with Neoarchean ages reported from the microblocks in the North China Craton. The zircon Lu–Hf data from the Yishui suite display εHf(t) values between -2.5 and 5.0, with corresponding model ages suggesting magma derivation from Neoarchean juvenile sources together with limited reworked Paleo-Mesoarchean crustal components.

Our study is the first report of Neoarchean suprasubduction-type ophiolites from a locality far from the margins of the major crustal blocks and suture zones in the NCC and strengthens the concept that the craton is a mosaic of several microblocks with intervening oceans that closed along multiple subduction zones. We envisage that the amalgamation between the Xuhuai and the Jiaoliao microblocks resulted in the accretion of the Yishui suprasubduction zone ophiolitic assemblages onto the southern margin of the Jiaoliao microblock. The Neoarchean microblock amalgamation in the North China Craton provides new insights into continental growth in the early Earth and confirms that modern style plate tectonics might have been initiated early in the history of our planet.

Tuesday, November 24, 2015

Great Oxygenation Event had a Precedessor 100 Million Years Earlier

Earth scientists from the University of Alberta, University of Waterloo, Arizona State University, University of California Riverside, and Georgia Institute of Technology have found evidence that Earth's transition to a permanently oxygenated atmosphere was anything but smooth.

Their paper, published this month in Science Advances, uses geochemical data from sedimentary rocks in Western Australia to show that a burst of O2 production by photosynthetic cyanobacteria temporarily increased O2 concentrations in Earth's atmosphere and shallow oceans roughly 2.5 billion years ago.

"We are tracking atmospheric changes through time to understand how oxygen increased to the level needed to support complex life," says Rob Creaser, professor of earth and atmospheric sciences at the University of Alberta. "When the Earth first formed, there was no oxygen in the atmosphere. Our analytical facilities here at the U of A allowed us to conduct precise analyses of this rock sample to understand the tempo at which that oxygen built up through photosynthesis.

Creaser's lab at the University of Alberta in the Canadian Centre for Isotopic Microanalysis is one of only a few in the world with the ability to take the precise measurements of osmium needed to conduct this type of analysis. "Without this type of facility, we wouldn't be able to write this paper or investigate this process."

The new data suggest that O2 levels in the Earth's atmosphere fluctuated until enough O2 finally accumulated to create a permanently oxygenated atmosphere around 2.4 billion years ago, a transition widely known as the "Great Oxidation Event." "The onset of Earth's surface oxygenation may have been a complex process characterized by multiple 'whiffs' of O2 until a tipping point was crossed," says Creaser's former PhD student and UAlberta alumnus Brian Kendall, a professor of Earth and Environmental Sciences at the University of Waterloo and lead author on the paper.


Wednesday, November 18, 2015

Evidence of Subduction During the NeoArchean

Petrogenesis of intermediate volcanic assemblages from the Shebandowan greenstone belt, Superior Province: Evidence for subduction during the Neoarchean

Author:

Lodge

Abstract:

Research on the petrogenesis of andesites and their implications for geodynamic setting are an important facet to understanding controversial tectonic processes during the Archean. The genesis of Archean intermediate volcanic rocks and their relationship to mantle- and crust-derived melts can either support subduction-dominated tectonic processes or plume-crust interactions. This study describes the lithogeochemistry and Nd-isotopic composition of intermediate volcanic assemblages in the Shebandowan greenstone belt of the Wawa-Abitibi terrane that were deposited prior to deformation and tectonic assembly of the Superior Province. The intermediate rocks of the Shebandowan greenstone belt are unique in that they are voluminous, are relatively weakly deformed and are low metamorphic grade, and contain significant amounts of magnesian andesites and adakites.

The major and trace element geochemistry of the intermediate assemblages share many of the geochemical characteristics of modern volcanic and continental arcs. These features include enriched Th/Nb and Th/La ratios, steeply dipping rare earth patterns, and pronounced negative Ti and Nb anomalies on primitive mantle-normalized diagrams. Additionally, these rocks also contain distinct positive Pb and Cs anomalies without evidence of major mobility of these elements during secondary processes. Neodymium isotopic analyses indicate the interaction with older crust and show good correlations with evolved Nd-isotopic values with other crustal contamination proxies such as Th/Ce and Ti/Sc ratios. Modelling mixing and assimilation-fractional crystallization interactions between plume-derived and crustal melts reveal that plume-crust interactions cannot explain the compositional array obtained from the intermediate rocks in the Shebandowan greenstone belt.

A compilation of U-Pb geochronology for the Shebandowan greenstone belt reveals that tholeiitic/komatiite dominated strata are slightly older than the intermediate-dominated strata. Given that these domains are structurally separated, it is very likely that the Shebandowan greenstone belt was formed in two different geodynamic settings. These different geodynamic settings have important implications for the metallogeny of the belt and explain the relative enrichment of Au and Ni-Cu mineralization in the Shebandowan greenstone belt relative to other ca. 2720 Ma assemblages in the Wawa-Abitibi terrane.

Monday, October 05, 2015

The Archean Banded Iron Formations of Krivoy Rog, Ukraine

Geochemistry of the Krivoy Rog Banded Iron Formation, Ukraine, and the impact of peak episodes of increased global magmatic activity on the trace element composition of Precambrian seawater

Authors:

Viehmann et al

Abstract:

Pure Superior-type Banded Iron Formation (BIF) samples from the Krivoy Rog Supergroup (Ukraine) are excellent archives of ambient Early Precambrian seawater. They show low concentrations of incompatible elements such as Zr, Hf, and Th, and shale-normalized Rare Earths and Yttrium (REYSN) patterns similar to those of modern seawater, i.e. heavy REYSN enriched patterns with positive LaSN, GdSN and YSN anomalies. Lack of CeSN and presence of positive EuSN anomalies indicate REY contributions to anoxic ferruginous seawater from high-temperature hydrothermal fluids.

The depositional age of the Krivoy Rog BIF is ill-defined, but a Late Archean to Paleoproterozoic age has been suggested based on U–Pb zircon ages for units stratigraphically above and below the BIF. We determined Sm–Nd isotopic compositions of pure and impure samples from the Krivoy Rog BIF, which yield an errorchron with an apparent age of 2406 ± 350 Ma (MSWD 15), that falls within this broad age range. All pure BIF samples show chondrite-normalized (subscript CN) REY patterns with strong positive EuCN anomalies that are typical for Archean but rather rare and much less pronounced in Proterozoic BIFs. Associated schists also show Archean – rather than post-Archean-style REY distributions. The REY geochemistry of both, chemical and epiclastic sediments, therefore, is more consistent with a Late Archean rather than a post-Archean depositional age of the Krivoy Rog Supergroup.

Initial ɛNd values of impure BIFs and of associated schist reveal variable contributions from TTGs less radiogenic in Nd and a more radiogenic component possibly comprised of basement amphibolites or mafic volcanics of the stratigraphically underlying New Krivoy Rog Group. The purest Krivoy Rog BIF, representing local Krivoy Rog seawater, displays an ɛNd2.60 Ga value of −2.3. This value is less radiogenic than impure Krivoy Rog BIFs or other near-contemporaneous Neoarchean pure chemical sediments. To preserve this specific local isotopic fingerprint in anoxic Archean seawater, the Krivoy Rog BIF must have been deposited in an isolated sea basin with limited exchange with ferruginous deep-waters of the open ocean.

A compilation of REY data for high-purity Precambrian BIFs reveals that EuCN/Eu*CN ratios of Precambrian seawater follow a general global evolution curve, that shows specific peaks which reflect times of increased high-temperature hydrothermal REY input into seawater. Following declining EuCN/EuCN ratios from the Eoarchean to the Mesoarchean, the ratios suddenly rise at 2.7 Ga and reach a maximum at 2.6 Ga, indicating an increased flux of high-temperature hydrothermal REY to Neoarchean seawater, which supports the hypothesis that times of widespread BIF deposition coincided with periods of intense submarine hydrothermal activity, probably triggered by major mantle plume events. This association is supported by a strong increase of the ɛNd(t) values of pure seawater archives at 2.7–2.6 Ga, which reflects an increased flux of mantle Nd into seawater. These results suggest that Eu-REY systematics (and potentially ɛNd systematics) are robust tools to indentify episodes of enhanced mantle plume activity.

Thursday, June 18, 2015

Ubiquitous Basaltic-derived Paleosols From Neo Archean Australia

Ubiquitous occurrence of basaltic-derived paleosols in the Late Archean Fortescue Group, Western Australia

Authors:

Teitler et al

Abstract:

The 2.76 Ga old Mount Roe Basalt paleosols (MR#1 and MR#2), recognized near the base of the 2.76–2.69 Ga Fortescue Group in Western Australia, represent some of the oldest definite examples of Archean paleoweathering profiles. The loss of Fe and the absence of pedogenic carbonates in these reference paleosols have been considered as strong evidence for low oxygen and moderate carbon dioxide in the Late Archean atmosphere, respectively. However, the robustness of such interpretations suffers both from the scarcity of paleosol exposures and the superposition of post-weathering alteration over primary soil profiles. Here we report new exposures of the MR#1 paleosol as well as a number of new basalt-derived paleosol occurrences distributed in the Mount Roe Basalt and the 2.73 Ga old Kylena Formations of the Fortescue Group. We show that all these paleosols, including MR#1 and MR#2, were strongly affected by post-weathering reductive alteration. Nevertheless, we discovered early lithologic units, locally preserved within the hydrothermally altered paleosols, which feature distinct chemical and mineralogic compositions. These include: (i) 13C-depleted carbonaceous-rich, diaspore–pyrophyllite boudins likely inherited from the hydrolysis and bauxitization of the parent basalt and (ii) green hard core material, mostly composed of Fe–sericite associated with authigenic sphene and containing early relics of sulfate-bearing iron-rich smectite or berthierine. We argue that smectite relics may constitute a part of the primary pedogenic mineral assemblage, while berthierine and sphene formed during diagenesis through the circulation of reductive fluids. Because the depletion of iron observed in the Fortescue paleosols is not solely due to pedogenesis, but also to post-weathering alteration, particular care has to be taken when bulk chemical profiles of iron in such paleosols are used as atmospheric paleobarometer. Recognition of the regional-scale, syn-depositional alteration of the Fortescue subaerial basalts over the north Pilbara suggests the onset of intense continental weathering associated with the uplift and emergence of the Pilbara craton during continental break-up and rifting. Such a regional onset of continental weathering may have provided large amounts of nutrients to nearby marine and/or lacustrine systems, favoring the development of microbial life in shallow waters.

Monday, June 08, 2015

Evidence of Atmospheric Oxygen in NeoArchean Before the Great Oxygenation Event


Geochemical stratigraphy, sedimentology, and Mo isotope systematics of the ca. 2.58–2.50 Ga-old Transvaal Supergroup carbonate platform, South Africa

Authors:

Eroglu et al

Abstract:

The Neoarchean-Paleoproterozoic Transvaal Supergroup in South Africa contains the well-preserved stromatolitic Campbellrand-Malmani carbonate platform, which was deposited in shallow seawater shortly before the 2.40–2.32 Ga Great Oxidation Event (GOE). This platform is composed of alternating stromatolitic carbonates and mudstones and is a prominent candidate for (isotope-) geochemical mapping to investigate the appearance of very small amounts of free oxygen that accumulated in shallow waters preceding the GOE. Mo isotopes in sedimentary archives are widely used as a proxy for redox-changes in modern and ancient environments and recent evidence suggests that oxy-molybdate (MoO42−) is directly transferred from ocean water to inorganic carbonates with negligible fractionation, thus reflecting oceanic Mo isotope signatures.

In this study we analyzed major and trace element compositions as well as Mo isotopic compositions of carbonate and mudstone samples from the KMF-5 drill core. Geochemical indicators, such as Fe and Mn concentrations and Fe-to-Mn abundance ratios reveal the preservation of some geochemical indicators despite the widespread silicification and dolomitization of the platform. Heavy δ30Si values of silicified carbonates between 0.53 and 2.35‰ point to Si precipitation from surface water during early diagenesis rather than to a later hydrothermal overprint. This assessment is supported by the frequent observation of rip-up structures of silica (chert) layers within the entire sedimentary succession. The δ98Mo values of whole rock samples throughout the Malmani-Campbellrand platform range between −0.82 and +1.40‰, similar to values reported for deeper slope carbonates from the Griqualand West area, but variations are independent from lithology or depositional water depth. These large variations in δ98Mo values indicate molybdenum redox cycling and thus the presence of free oxygen in the atmosphere-ocean system at that time, in agreement with earlier Mo isotopic studies on Campbellrand carbonates and shales. A similar range in δ98Mo values for carbonates between +0.40 and +0.87‰, however, was also found on the hand specimen scale, indicating the danger of a sample bias on the Mo isotopic stratigraphy of this carbonate platform. Results of previously unpublished adsorption experiments of Mo on CaCO3 clearly indicate that the Mo inventory of Malmani-Campbellrand carbonates was not only influenced by primary adsorption from seawater, but to a much larger degree by secondary processes during early diagenesis, which also affected the Mo isotopic composition of the samples on a local scale. Our results indicate that Mo concentrations and isotopic compositions in ancient stromatolitic carbonates were subject to redox changes within microbial mats and within the soft sediment during early diagenesis and later lithification, and as such cannot be used to quantitatively reconstruct the amount of free atmospheric oxygen or its fluctuations through Earth's history. Nevertheless, we interpret our heavy Mo isotopic signatures from carbonates as a minimum value for Neoarchean seawater and reinforce the assumption that free atmospheric oxygen built up a heavy oceanic Mo reservoir at that time.

Friday, February 06, 2015

Evidence of Pre Great Oxidation Event Aerobic Photosynthesis

Selenium isotopes support free O2 in the latest Archean

Authors:

Stüeken et al

Abstract:

Selenium (Se) undergoes redox transformations and isotopic fractionations at relatively high redox potentials and could therefore provide insight into changes in oceanic and atmospheric O2 levels over Earth's history. We test this idea with Se data from the 2.5 Ga Mount McRae Shale (Hamersley Basin, Australia), which records temporary enrichments in abundances and isotopes of other redox-sensitive elements indicating a "whiff of oxygen" in Earth's atmosphere before the Great Oxidation Event. Se isotopic ratios expressed as δ82/78Se and abundances relative to crustal background show significant positive excursions of up to 1.1‰ and an enrichment 13 times above background, respectively, overlapping with excursions in Mo and N isotopes and abundances. Because Se has a relatively high redox potential and photosynthetic oxidation pathways are unknown, our data thus suggest that Se was mobilized by free O2 during this interval. The isotopic fractionation likely occurred during transport of Se oxyanions from the site of weathering to the outer shelf. Although O2 could have been produced locally on land and may not necessarily have increased in the global atmosphere, our results strengthen the inference of an early origin of oxygenic photosynthesis long before the Paleoproterozoic Great Oxidation Event. This is the first report of a Se isotope excursion in the Precambrian rock record, and it confirms that Se isotopes can serve as a useful redox proxy in deep time.

Wednesday, December 31, 2014

NeoArchean Skjoldungen Orogen Appears to be a Modern Continental Collision


Exhumation rates in the Archean from pressure–time paths: Example from the Skjoldungen Orogen (SE Greenland)

Authors:

Berger et al

Abstract:

The discussions on the orogenic evolution during Earth's history converge to the question of a different thermal structure in the Archean compared to the Phanerozoic and the applicability of the plate tectonic paradigm. However, geothermal structures are transient in orogens and are difficult to translate into large-scale tectonics and exhumation rates. Therefore, we propose depth–time data in the Archean Skjoldungen Orogen (SE Greenland, North Atlantic Craton) that allow for reconstruction of an exhumation rate independent of geothermal gradients. The resulting exhumation rate of ca. 0.4 km/Ma is similar to exhumation rates during erosion-controlled processes in modern orogens. These exhumation rates can only be established by erosion time constants similar to modern orogens. The occurrence of erosion-controlled exhumation is best explained by a stiff foreland promoting localized deformation in the orogen. Therefore, a switch from magmatic-dominated processes to localized deformation is proposed in the Skjoldungen Orogen area. This is supported by a change in magma composition and volume, from widespread granodiorite to localized alkaline intrusions. In addition, the involved metasedimentary rocks include detrital zircons of the only 50 Ma older foreland, which also correspond to erosion and tectonics as in modern orogens, i.e. flysh-type sediments. Relatively fast exhumation rates and the structural-magmatic evolution of the Neoarchean Skjoldungen Orogen thus indicate modern-style tectonic processes where stiff Mesoarchean continental crust forms a foreland to a collisional orogen instead of typical accretionary tectonics of weak island arc-like terranes in granite-greenstone terranes.

Tuesday, December 30, 2014

Evidence of Tidal Deposits From NeoArchean India


Late Archean tidalites from western margin of Chitradurga Greenstone Belt, southern India

Authors:

Bhattacharya et al

Abstract:

Tidalites are preserved within a metavolcano-sedimentary succession of the Late Archean Bababudan Group (Dharwar Supergroup) along the western boundary of the NNW-SSE trending Chitradurga greenstone belt, West Dharwar Craton, southern India. These may represent the oldest record of tidal processes in peninsular India. Millimetre thick sand-mud alternations, bidirectional cross-strata, mudstone-draped sandy foresets, reactivation surfaces indicating time-velocity asymmetry, sigmoidal cross-strata and mudstone draped flaser/lenticular bedding are displayed by the sandstone mudstone heterolithic facies in the upper part of the Bababudan succession, together implying a tidal depositional system. Thick-thin pairs of rhythmic foreset bundles correspond to neap-spring tidal cycles within a semidiurnal tidal system. Development of the studied coastal sediments suggests formation of stable platform along the western margin of the late Archean Chitradurga greenstone belt.