Titan's Lakes Appear to Have Floating Hydrocarbon Ice

It's not exactly icing on a cake, but it could be icing on a lake. A new paper by scientists on NASA's Cassini mission finds that blocks of hydrocarbon ice might decorate the surface of existing lakes and seas of liquid hydrocarbon on Saturn's moon Titan. The presence of ice floes might explain some of the mixed readings Cassini has seen in the reflectivity of the surfaces of lakes on Titan.

"One of the most intriguing questions about these lakes and seas is whether they might host an exotic form of life," said Jonathan Lunine, a paper co-author and Cassini interdisciplinary Titan scientist at Cornell University, Ithaca, N.Y. "And the formation of floating hydrocarbon ice will provide an opportunity for interesting chemistry along the boundary between liquid and solid, a boundary that may have been important in the origin of terrestrial life."

Titan is the only other body besides Earth in our solar system with stable bodies of liquid on its surface. But while our planet's cycle of precipitation and evaporation involves water, Titan's cycle involves hydrocarbons like ethane and methane. Ethane and methane are organic molecules, which scientists think can be building blocks for the more complex chemistry from which life arose. Cassini has seen a vast network of these hydrocarbon seas cover Titan's northern hemisphere, while a more sporadic set of lakes bejewels the southern hemisphere.

Up to this point, Cassini scientists assumed that Titan lakes would not have floating ice, because solid methane is denser than liquid methane and would sink. But the new model considers the interaction between the lakes and the atmosphere, resulting in different mixtures of compositions, pockets of nitrogen gas, and changes in temperature. The result, scientists found, is that winter ice will float in Titan's methane-and-ethane-rich lakes and seas if the temperature is below the freezing point of methane -- minus 297 degrees Fahrenheit (90.4 Kelvins). The scientists realized all the varieties of ice they considered would float if they were composed of at least 5 percent "air," which is an average composition for young sea ice on Earth. ("Air" on Titan has significantly more nitrogen than Earth air and almost no oxygen.)

If the temperature drops by just a few degrees, the ice will sink because of the relative proportions of nitrogen gas in the liquid versus the solid. Temperatures close to the freezing point of methane could lead to both floating and sinking ice - that is, a hydrocarbon ice crust above the liquid and blocks of hydrocarbon ice on the bottom of the lake bed. Scientists haven't entirely figured out what color the ice would be, though they suspect it would be colorless, as it is on Earth, perhaps tinted reddish-brown from Titan's atmosphere.

"We now know it's possible to get methane-and-ethane-rich ice freezing over on Titan in thin blocks that congeal together as it gets colder -- similar to what we see with Arctic sea ice at the onset of winter," said Jason Hofgartner, first author on the paper and a Natural Sciences and Engineering Research Council of Canada scholar at Cornell. "We'll want to take these conditions into consideration if we ever decide to explore the Titan surface some day."

Cassini's radar instrument will be able to test this model by watching what happens to the reflectivity of the surface of these lakes and seas. A hydrocarbon lake warming in the early spring thaw, as the northern lakes of Titan have begun to do, may become more reflective as ice rises to the surface. This would provide a rougher surface quality that reflects more radio energy back to Cassini, making it look brighter. As the weather turns warmer and the ice melts, the lake surface will be pure liquid, and will appear to the Cassini radar to darken.

Mars Has Plate Techtonics

For years, many scientists had thought that plate tectonics existed nowhere in our solar system but on Earth. Now, a UCLA scientist has discovered that the geological phenomenon, which involves the movement of huge crustal plates beneath a planet's surface, also exists on Mars.

"Mars is at a primitive stage of plate tectonics. It gives us a glimpse of how the early Earth may have looked and may help us understand how plate tectonics began on Earth," said An Yin, a UCLA professor of Earth and space sciences and the sole author of the new research.

Yin made the discovery during his analysis of satellite images from a NASA spacecraft known as THEMIS (Time History of Events and Macroscale Interactions during Substorms) and from the HIRISE (High Resolution Imaging Science Experiment) camera on NASA's Mars Reconnaissance Orbiter. He analyzed about 100 satellite images — approximately a dozen were revealing of plate tectonics.

Yin has conducted geologic research in the Himalayas and Tibet, where two of the Earth's seven major plates divide.

"When I studied the satellite images from Mars, many of the features looked very much like fault systems I have seen in the Himalayas and Tibet, and in California as well, including the geomorphology," said Yin, a planetary geologist.

For example, he saw a very smooth, flat side of a canyon wall, which can be generated only by a fault, and a steep cliff, comparable to cliffs in California's Death Valley, which also are generated by a fault. Mars has a linear volcanic zone, which Yin said is a typical product of plate tectonics.

"You don't see these features anywhere else on other planets in our solar system, other than Earth and Mars," said Yin, whose research is featured as the cover story in the August issue of the journal Lithosphere.

The surface of Mars contains the longest and deepest system of canyons in our solar system, known as Valles Marineris (Latin for Mariner Valleys and named for the Mariner 9 Mars orbiter of 1971󈞴, which discovered it). It is nearly 2,500 miles long — about nine times longer than the Earth's Grand Canyon. Scientists have wondered for four decades how it formed. Was it a big crack in Mars' shell that opened up?

"In the beginning, I did not expect plate tectonics, but the more I studied it, the more I realized Mars is so different from what other scientists anticipated," Yin said. "I saw that the idea that it is just a big crack that opened up is incorrect. It is really a plate boundary, with horizontal motion. That is kind of shocking, but the evidence is quite clear.

"The shell is broken and is moving horizontally over a long distance. It is very similar to the Earth's Dead Sea fault system, which has also opened up and is moving horizontally."

The two plates divided by Mars' Valles Marineris have moved approximately 93 miles horizontally relative to each other, Yin said. California's San Andreas Fault, which is over the intersection of two plates, has moved about twice as much — but the Earth is about twice the size of Mars, so Yin said they are comparable.

Yin, whose research is partly funded by the National Science Foundation, calls the two plates on Mars the Valles Marineris North and the Valles Marineris South.

"Earth has a very broken 'egg shell,' so its surface has many plates; Mars' is slightly broken and may be on the way to becoming very broken, except its pace is very slow due to its small size and, thus, less thermal energy to drive it," Yin said. "This may be the reason Mars has fewer plates than on Earth."

Mars has landslides, and Yin said a fault is shifting the landslides, moving them from their source.

Does Yin think there are Mars-quakes?

"I think so," he said. "I think the fault is probably still active, but not every day. It wakes up every once in a while, over a very long duration — perhaps every million years or more."

Yin is very confident in his findings, but mysteries remain, he said, including how far beneath the surface the plates are located.

"I don't quite understand why the plates are moving with such a large magnitude or what the rate of movement is; maybe Mars has a different form of plate tectonics," Yin said. "The rate is much slower than on Earth."

The Earth has a broken shell with seven major plates; pieces of the shell move, and one plate may move over another. Yin is doubtful that Mars has more than two plates.

"We have been able to identify only the two plates," he said. "For the other areas on Mars, I think the chances are very, very small. I don't see any other major crack."

Link. Paper link.

Does Titan Have an Europa-style Interior Ocean?

In the seven years Cassini has spent orbiting Saturn, the spacecraft has sent back mountains of data that has changed our view of the ringed planet and its moons. Saturn's largest moon, Titan, has been a particular focus of attention because of its dense, complex atmosphere, its weather and its lakes and oceans.

Now it looks as if Titan is even stranger still. The evidence comes from careful observations of Titan's orbit and rotation. This indicates that Titan has an orbit similar to our Moon's: it always presents the same face towards Saturn and its axis of rotation tilts by about 0.3 degrees.

Together, these data allow astronomers to work out Titan's moment of inertia and this throws up something interesting. The numbers indicate that Titan's moment of inertia can only be explained if it is a solid body that is denser near the surface than it is at its centre.

That's just plain weird--unthinkable really, given what we know about how planets and moons form.

But there is another explanation, however: that Titan isn't solid at all.

Today, Rose-Marie Baland and buddies at the Royal Observatory of Belgium in Brussels, crunch some numbers to see whether a liquid model is compatible with the measured moment of inertia. "We assume the presence of a liquid water ocean beneath an ice shell and consider the gravitational and pressure torques arising between the different layers of the satellite," they say.

Their conclusion is that Titan's moment of inertia could well be explained by the presence of liquid ocean beneath an icy shell.

no time, but intriguing. I think it'd need to work for methane rather than water though.

Paper here.

Was the Early Earth Chondritic or Not?

Researchers have found a primitive Earth mantle reservoir on Baffin Island in the Canadian Arctic. Geologist Matthew Jackson and his colleagues from a multi-institution collaboration report the finding--the first discovery of what may be a primitive Earth mantle--this week in the journal Nature.

The Earth's mantle is a rocky, solid shell that is between the Earth's crust and the outer core, and makes up about 84 percent of the Earth's volume. The mantle is made up of many distinct portions or reservoirs that have different chemical compositions.

Scientists had previously concluded that the Earth was slightly older than 4.5 billion years old, but had not found a piece of the Earth's primitive mantle.

Until recently, researchers generally thought that the Earth and the other planets of the solar system were chondritic, meaning that the mantle's chemistry was thought to be similar to that of chondrites--some of the oldest, most primitive objects in the solar system. Assuming a chondritic model of the Earth, a piece of the primitive mantle would have certain isotope ratios of the chemical elements of helium, lead and neodymium.

The model that the Earth was chondritic was called into question with a discovery five years ago by a team at the Carnegie Institution of Washington, which suggested the ratio of neodymium on Earth was higher than what would be expected if the Earth were indeed chondritic.

That finding changed the neodymium ratio expected in the primitive mantle and in turn, changed where researchers should be looking to find evidence of a primitive mantle. According to the lead author, Matthew Jackson, "We had been looking under the wrong rock."

Since many of the ancient rocks have melted over time, finding a piece of the primitive mantle means studying lavas. Lavas retain the same isotopic composition of the rocks that have melted into the lava. Therefore, testing the lava's composition is identical to testing the original rock's composition.

When the assumption about the neodymium ratio was altered, Jackson and his colleagues knew they should take a look at lava samples from Baffin Island, since those samples contained the correct ratios of helium and neodymium. They discovered that the lavas also had the correct ratio for lead. The lead isotopes suggest that the samples from Baffin Island date the lava's mantle source reservoir to between 4.55 and 4.45 billion years old, only a little younger than the age of the Earth. The lava sample comes from an ancient rock that melted 62 million years ago.

When the researchers studied the composition of the lava found at Baffin Island, they discovered that the sample had the correct ratios of all three chemical elements--helium, lead, and the new non-chronditic neodymium ratio. This discovery suggests that the sample from Baffin Island is the first evidence for the oldest mantle reservoir.

This study challenges the idea that the Earth has a chondritic primitive mantle and according to Matthew Jackson is, "suggesting an alternative." One possibility, according to Jackson, is that "the early Earth went through a differentiation event and the Earth's crust was extracted from the early mantle and is now hidden in the deep earth; the hidden crust and the mantle found on Baffin Island would sum to chondritic."

Big potential wrinkle there.

Quick Question

Has anyone ever done the calculation of just how much water has been lost from the Earth over the Phanerozoic? I mean through UV light slighting the water molecules up high and the hydrogen escaping because of its low mass and the Earth's warmth relative to gravity? I have heard discussions of this with respet to Venus, but not Earth...my google fu isn't so good today.