Evidence of Ethane in Titan's Atmosphere

Titan's atmosphere as observed by VIMS/Cassini solar occultations: CH4, CO and evidence for C2H6 absorption

Authors:

Maltagliati et al

Abstract:

We present an analysis of the VIMS solar occultations dataset, which extracts vertically resolved information on the characteristics of Titan's atmosphere between 100-700 km with a characteristic vertical resolution of 10 km. After a series of data treatment procedures to correct problems in pointing stability and parasitic light, 4 occultations out of 10 are retained. This sample covers different seasons and latitudes of Titan. Through the inversion of the transmission spectra with a line-by-line radiative transfer code we retrieve the vertical distribution of CH4 and CO mixing ratio. The two methane bands at 1.4 and 1.7 {\mu}m are always in good agreement and yield an average stratospheric abundance of 1.28±0.06%. This is significantly less than the value of 1.48% obtained by the GCMS/Huygens instrument. The analysis of the residual spectra after the inversion shows that there are additional absorptions which affect a great part of the VIMS wavelength range. We attribute many of these additional bands to gaseous ethane, whose near-infrared spectrum is not well modeled yet. Ethane contributes significantly to the strong absorption between 3.2-3.5 {\mu}m that was previously attributed only to C-H stretching bands from aerosols. Ethane bands may also influence the surface windows, especially at 2.7 {\mu}m. Other residual bands are generated by stretching modes of C-H, C-C and C-N bonds. In addition to the C-H stretch from aliphatic hydrocarbons at 3.4 {\mu}m, we detect a strong and narrow absorption at 3.28 {\mu}m which we tentatively attribute to the presence of PAHs in the stratosphere. C-C and C-N stretching bands are possibly present between 4.3-4.5 {\mu}m. Finally, we obtained the CO mixing ratio between 70-170 km. The average result of 46±16 ppm is in good agreement with previous studies.