Showing posts with label iridium. Show all posts
Showing posts with label iridium. Show all posts

Thursday, March 24, 2016

A Contrarian K-Pg/KT Mass Extinction Root Cause Proposal

End-cretaceous cooling and mass extinction driven by a dark cloud encounter

Authors:


Nimura et al

Abstract:


We have identified iridium in an ~5 m-thick section of pelagic sediment cored in the deep sea floor at Site 886C, in addition to a distinct spike in iridium at the K-Pg boundary related to the Chicxulub asteroid impact. We distinguish the contribution of the extraterrestrial matter in the sediments from those of the terrestrial matter through a Co-Ir diagram, calling it the "extraterrestrial index" fEX. This new index reveals a broad iridium anomaly around the Chicxulub spike. Any mixtures of materials on the surface of the Earth cannot explain the broad iridium component. On the other hand, we find that an encounter of the solar system with a giant molecular cloud can aptly explain the component, especially if the molecular cloud has a size of ~100 pc and the central density of over 2000 protons/cm^3. Kataoka et al. (2013, 2014) pointed that an encounter with a dark cloud would drive an environmental catastrophe leading to mass extinction. Solid particles from the hypothesized dark cloud would combine with the global environment of Earth, remaining in the stratosphere for at least several months or years. With a sunshield effect estimated to be as large as -9.3 W m^-2, the dark cloud would have caused global climate cooling in the last 8 Myr of the Cretaceous period, consistent with the variations of stable isotope ratios in oxygen (Barrera and Huber, 1990; Li and Keller, 1998; Barrera and Savin, 1999; Li and Keller, 1999) and strontium (Barrera and Huber, 1990; Ingram, 1995; Sugarman et al., 1995). The resulting growth of the continental ice sheet also resulted in a regression of the sea level. The global cooling, which appears to be associated with a decrease in the diversity of fossils, eventually led to the mass extinction at the K-Pg boundary.

Thursday, February 25, 2016

Iridium Across the Triassic-Jurassic Boundary in Austria

Distribution of iridium and associated geochemistry across the Triassic–Jurassic boundary in sections at Kuhjoch and Kendlbach, Northern Calcareous Alps, Austria

Authors:

Tanner et al

Abstract:

Samples from strata spanning the Triassic–Jurassic boundary at the GSSP at Kuhjoch and at Kendlbachgraben were studied by NAA, XRF and combustion analysis to determine Ir levels and associated geochemistry. The results are compared to previously determined carbon isotope stratigraphy at these sections. Ir concentrations in the limestones of the Kössen Formation at Kuhjoch are very low (< 10 pg/g) below the top of the formation, rising to 26 pg/g, in the T-bed at the top of the Eiberg Member. The Tiefengraben Member of the Kendlbach Formation exhibits higher concentrations of Ir in general relative to the strata below. The shift to higher levels is abrupt at the base of the member, coinciding with a decrease in carbonate content. Concentrations of 60 to 80 pg/g are typical through the entire thickness of the Schattwald Beds and into the gray Tiefengraben Member strata, peaking at 145 pg/g. Concentrations decline to 30–40 pg/g above 680 cm from the formation base, coinciding with increasing carbonate content. The analyses from the Kendlbachgraben section compare well with those from Kuhjoch, with similar difference in Ir concentration between the Kössen and Kendlbach formations. In both sections, the initial increase in Ir corresponds to the initial carbon isotope excursion. Concentrations of redox-sensitive elements indicate transient reducing conditions during deposition of the uppermost Kössen Formation, but oxidizing conditions during Tiefengraben Member deposition. The Al/Ti ratio indicates more intense weathering during deposition of the lowermost 20 cm of the Tiefengraben Member, but otherwise consistently humid to sub-humid climate prevailed during deposition. The primary control on Ir concentration in the sampled section is formation lithology, although there are variations within the Tiefengraben Member that are independent of carbonate content. Enrichment of Ir at the top of the T-bed is associated with a redox boundary, but the cause of other variations is undetermined.